Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Transcribed Image Text:1.
Draw all products for the base-catalyzed E2-elimination shown below. What are their
relative stabilities? What is the possible side-reaction?
NaOEt
Br
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- 9. Identify the major product of each reaction and indicate whether the reaction is likely to proceed by a bimolecular (SN2) or a unimolecular (SN1) mechanism. Why is each reaction likely to proceed via the mechanism you have chosen? (Hint: The leaving groups -OSO2CF3 and -OMs are also sulfonates (like tosylate, -OTS), so they are also good leaving groups.) a) b) d) Oso₂CF, OMs Br Nal acetone NaCN DMF CH₂OH 80% H₂O, 20% ethanol -6-arrow_forward5. Predict the product(s) of the following E2 reactions. DBNarrow_forwardWhat is the predominant mechanism of the reaction below? SN2 SN1 E2 E1arrow_forward
- Please draw the most important resonance structure of the cationic intermediate leading to the MAJOR product of electrophilic bromination of this compoundarrow_forward10. For the following SN2 reactions, provide either the nucleophile or substrate necessary to complete the reaction: ? NaOH a tosylate A B C D 828 ? ? an alkyl chloride Br OH ? хотонarrow_forwardCan you provide a full reaction mechanism for this reaction? Bn is benzyl azide.arrow_forward
- What are the products of the catalytic hydrogenation reactions shown below? Explain the differences using key intermediates as needed. Na / NH3 H2 Lindlar Catalystarrow_forwardQ2. Write the step-by-step mechanism for the following reactions showing, initiation, propogation and atleast one termination rections. Br2 a) Br hv н Br Br2 b) hv D Br NaOH c) H2CCI2 CC2 NaCI H20 + + d) Br2 Br La Br. +arrow_forwardPlease explain the mechanism of the following reaction and why these products are formed in equal amounts. Oft D NABD4 (excess) then H30 work-up OH. OHarrow_forward
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