1. determine the type of pericyclic reaction (sigmatropic, electrocyclic, cycloaddition) 2. draw the mechanism for the reaction using curved arrows, and then use molecular orbital theory to evaluate the appropriate HOMO-LUMO interactions 3. determine the stereochemistry of the product, if necessary CHOOSE TWO OUT OF THE THREE PROBLEMS TO COMPLETE heat A RO, LOR 1. KH, THF RO, B RO .OR' 2. МеОН, Н20 OR' heat

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter8: Haloalkanes, Halogenation, And Radical Reactions
Section: Chapter Questions
Problem 8.21P
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1. determine the type of pericyclic reaction (sigmatropic, electrocyclic, cycloaddition)
2. draw the mechanism for the reaction using curved arrows, and then use molecular orbital theory to evaluate
the appropriate HOMO-LUMO interactions
3. determine the stereochemistry of the product, if necessary
CHOOSE TWO OUT OF THE THREE PROBLEMS TO COMPLETE
heat
A
RO,
LOR
КН, THF
RO,
в
-OH
ROH
...OR'
2. МеОн, Н,о
OR'
heat
Transcribed Image Text:1. determine the type of pericyclic reaction (sigmatropic, electrocyclic, cycloaddition) 2. draw the mechanism for the reaction using curved arrows, and then use molecular orbital theory to evaluate the appropriate HOMO-LUMO interactions 3. determine the stereochemistry of the product, if necessary CHOOSE TWO OUT OF THE THREE PROBLEMS TO COMPLETE heat A RO, LOR КН, THF RO, в -OH ROH ...OR' 2. МеОн, Н,о OR' heat
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