1. Consider the molecule, iodine pentafluoride, IF5 a) What is the point group of IF5? b) Find a reducible representation covering all translational, rotational, and vibrational modes of IF5. (Hint: Your character for the identity should be 18) c) Reduce this representation into the irreducible components and use a character table to divide the irreducible representations up into rotational, translational, and vibrational symmetries. d) Which vibrational modes will be IR active?

1. Consider the molecule, iodine pentafluoride, IF5 a) What is the point group of IF5? b) Find a reducible representation covering all translational, rotational, and vibrational modes of IF5. (Hint: Your character for the identity should be 18) c) Reduce this representation into the irreducible components and use a character table to divide the irreducible representations up into rotational, translational, and vibrational symmetries. d) Which vibrational modes will be IR active?

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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