Chemistry
Chemistry
10th Edition
ISBN: 9781305957404
Author: Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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1. A sample of an aspirin tablet weighing 78.79 g was titrated with 56.39 mL of a standardized Ba(OH)2 solution with a concentration of 0.7406. Determine the % of acetylsalicylic acid present in the aspirin sample.

2 HC9H7O4 + Ba(OH)2 --> Ba(C9H7O4)2 + 2H2O

acetylsalicylic acid = 180.158g/mol

2. 

An antihistamine sample, brompheniramine maleate, weighing 5.01234 g was dissolved in alcohol and decomposed with metallic sodium. The resulting solution was treated with 12.00mL of 0.3121M AgNO3 to precipitate all of the liberated bromide ions as AgBr. The excess AgNO3 remaining in the solution was titrated with 9.123mL of 0.2181M KSCN to reach the endpoint. What is the %Br in the sample?

Br- + Ag+ --> AgBr(s)

Ag+ + SCN- --> AgSCN(s)

Br = 79.904 g/mol

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