1 1-nonyne 1-chloro-4-iodobutane 2 1-decyne 5 1-chloro-5-iodopentane 1-tridecyne (C-13 alkyne) 6 1-chloro-7-iodoheptane Reagents NH3 d CO2 LIAIH4 / dry ether a Li / NH3 NaCN h H3O* / H20 e NaNH2 / NH3 f Cro3 / H3O* i Li* Cu(CH3)2 HO Synthetic path

2. Formulate the potential product(s), starting material or reagents of each of the following reactions. Write "no reaction" where appropriate. Use boxes to provide your answer. Draw structures; DO NOT write molecular formula or chemical name as your answer. a) b) d) OH Br NaBH4 EtOH NaNH, NaOH H₂O HMPA OH

Write the products formed as a result of the reactions given below.

3. Write the structural formulas for the reactants and products that will complete the esterification reactions below: +H a. CH;-CH,-c-OH + HO-CH,-CH, C-0-CH,

1. Draw the chemical structures of both Amiodarone and Levothyroxine. Label all of the organic chemical reactions between them (you can use arrows, etc to do this). Aswell as explain Goitre in your own words, the increased iodine from the Amiodarone and why TSH may increase and T3, T4 remain normal etc. -0-CH2 -CH2-N Amiodarone C;H5 CH2)3 CH3 но NH2 Levothyroxine HO. HO. ÑH2

Provide the missing organic structures. Include stereochemistry where appropriate. Do not draw inorganic by-products. H2, Pd Lindlar's catalyst Structure CH 1 equiv. Br2 CHCI3 2 equiv. NaNH2 Structure Structure A в H3C Part 1 Please draw all four bonds at chiral centers. Draw Structure A:

28(d) Give name(s) of major organic product(s) of the following reaction. 3. LDA 4. CH;CH2CH2CH,Br

Use the triacylglycerol depicted below to answer the questions that follow. Chain A Chain B Chain C (i) Draw the fatty acid that would result if Chain A was hydrolyzed from the triacylglycerol under basic conditions. (ii) Give the shorthand notation for the fatty acid that could be formed from Chain C). (e.g. XX:YY AX,Y,Zz...etc.) Chain B (iii) Hydrolysis of which chain(s) would provide an omega-6-fatty acid? Chain A Chain C

Please don't provide handwritten solution ....

Identity the following fatty acids (please do all parts; have already done the problem just want to confirm answers)