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- Order the following in increasing priority A. -C, -CH, -OL B. -CH3, -CH2OH, -CH2CH3 C. -C≡CH, -CH゠CH2, -CH゠OMatch the letters with the correct reagents می ملکی معیلی مله مه **All numerical values in answers should be subscript** a b C d e f g HO a OH Br, b ✓ [Choose ] DMP [Choose] 1. PhMgBr 2. H2O 1. MeMgBr 2.H2O 1. TsCl, base 2. tBuOH 1. BH3:THF 2. NaOH, H2O2 PBr3 1. Mg, O=C, H2O [ Choose ] [Choose ] OH [Choose ] OHH Br. H₂CH₂C H H Br t-BuOK t-BuOH "Br CH3 H NaCN DMF CH₂CH3 (CH3)3CO
- 17. Name the following alkynes. b. a H HーC三c- H-c=c- H H H. H d. H-cEc-CH,-CH3 -c=c- H- с—н H H .CH3 f. H2Ç .CH2 c-c=CH H3C. H H-C-H CH H-C C-C- -c- C-H CH3 H2C. H H Н-с-н CH2 H CH3 I-O- O-me following multistep synthesis of the target structure on right from the starting structure on the left choose the correct order of reagents. Ignore stereochemistry. To preview the image click here & Step 1 Step 2 Step 3 Br. 요 Step 4 Step 5 Step 1 Reagent(s) [Select] Step 2 Reagent(s) [Select] Step 3 Reagent(s) [Select] Step 4 Reagent(s) [Select] Step 5 Reagent(s) [Select]O Lov -Ō Na H₂C- H3 C H3C i_._ H3C-(H₂C)4 -CH3 + H₂C H₂O + H₂O O—(CH2)—CH + HO O= -OH (CH2),—CH3+ HỌ + HO-(CH2)4-CH3 HT
- H3C- -Br + а. b. H3C CH3 2 CH3CH,NH2HgSO4 H2SO4, H20 1T (1) Br H2O2, NaOH 10 NaNH2 BH3, THE H =H 1S NH3 H20 HCI (1 equiv.) diethyl ether 1V 1W Br2 (m) MgBr (H,C=CH),CULI NaOCI ТСРВА > 1X 1Y > 1Z CH3COOH 1AA diethyl ether SoCI2, pyridine diethyl ether 1ABDetermine the one or two steps it takes to get from the starting material to the product using the reactions found in this chapter. HC-C HO, a. HC, HO CH2-OH b. СH, — CH—СH,—CH—CH, ČH,-CH3 CH2 || CH3-CH-CH,-Ĉ-CH3 ČH,-CH3 Br c. CH;-CH,-C=CH2 CH,-CH,-C-CH; ČH3
- 12) Which structure is different from the compound (I) ? CH₂ CH₂- H H a H CH(CH3)2 H. H CH₂ CH₂ H b -CH(CH₂)2 CH₂ CH₂- H H C H CH(CH₂)2 H7 CH₂ CH₂ CH(CH3)2 dRank the following groups in order of decreasing priority. a. – COOH, – H, – NH2, – OH b. – H, – CH3, – Cl, – CH2CI c. -CH2CH3, -CH3, -H, -CH(CH3)2 d. – CH = CH2, – CH3, – C ≡ CH, – HMaps 1. Choose the correct STARTING MATERIAL CH3 CH3 H3C CH3 CH3 Cl2/CH;Cl2 H3C-C-CH3 H-C-CH2CH3 H3C-C-CH2CI H2C–CH2 hv CH3 CH3 CH3 RAT BAT MAT Answer: [Select ] 2. Choose the correct REAGENT RAT. HCI BAT. Cl/CHCI3, hv MAT. Cl2, H20 .CI CI CI Answer: [Select ] 3. Choose the correct MAJOR PRODUCT H2, Ni RAT BAT MAT