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Zirconium: Jacinth Stone On The Jerusalem Wall

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History:
The history of zirconium all started with a stone that was initially used on the Jerusalem wall. The jacinth stone was the same mineral referred to by the Persians as zargun, meaning "gold-like" in Persian. 1
Jons Jacob Berzelius was the second chemist in history attempting to isolate zirconium and he was unable to obtain its pure form. Jons Jacob Berzelius experimented with impure zirconium by heating potassium hexafluorozirconate with a potassium metal enclosed in an iron tube. After analyzing the final outcome Berzellius was able to view a tiny amount of black powder, which was (K2ZrF6). Anton Eduard Van Arkel and Jan Hendrik de Boer were successful in the isolation of zirconium. Van Arkel was able to purify a transition metal by using a sublimation process. Hendrik de Boer was intrigued with Anton Eduard’s method and decided to try a similar approach in separating hafnium and zirconium. The first attempt of purification of zirconium using chlorides was not successful. In 1925, Arkel and Hendrik de Boer were able to obtain pure metallic zirconium by using a crystal bar process, also known as an Iodide …show more content…

John. A. Avers conducted a purification experiment of Zirconium via ion exchange to determine the percentage of recovery of the element. John A. Avers used various resins to determine which would obtain the highest purification of zirconium compared to other ion exchange resins and the extraction of the element will be conducted by using Zirconium from ores. Some of the resins used consisted of rare earths, beryllium, titanium and iron. John A. Ayers took zirconium ore’s and broke them down by using concentrated sulfuric acid. 8 Once the zirconium ore was broken down, the soluble zirconium was then converted to its nitrate form, Zr(NO3)4. The zirconium nitrate is then passed through a column containing a resin. The hydrogen form of Amberlite I.R.-100 was used as the

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