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Freezing Point Depression Lab Report

Decent Essays

Norah Albaiz
CHMY143-016
Katie Link
Lab Partner: Lydia Aman

Freezing Point Depression Measurements
Purpose:
The purpose of the experiment was to determine the molar mass of three unknown solutes by measuring the freezing point depression of a solution containing each of the unknowns. When a solute is dissolved in a solvent, the vapor pressure of the solvent is lowered. As a result of the decrease in the vapor pressure, the colligative properties change.
Colligative properties include vapor pressure lowering, boiling point elevation, freezing point depression and changes in osmotic pressure. Colligative properties are physical properties because they are dependent only upon the number of particles of solute that are dissolved in the solvent …show more content…

Factory calibration was used for the thermistor. Time was placed on the horizontal axis of the graph, and temperature on the vertical axis. The digital precision was set at two digits past the decimal point.

A plastic transfer pipette was used to put approximately 2 mL of p-xylene, obtained from the fume hood, into a clean, dry polypropylene test tube. The calibrated temperature probe was dried carefully with a paper towel, and then was put in the test tube. The measurement program was started and the test tube was lowered into an ice water bath, with the p-xylene in the test tube being below the surface level of the ice water. The p-xylene was stirred continuously with the temperature probe until the temperature graph leveled off. The program was stopped and the data was taken for 10 or 15 seconds after the graph leveled off. The p-xylene test tube was put in a beaker until the p-xylene thawed, and then was poured into the waste jar. The test was put in the box provided for used test tubes in the fume hood. To determine the freezing point of p-xylene, the range of data where the temperature had leveled off was used to obtain the average by clicking on Column …show more content…

3 to MM solute= Kf(grams solute)/[ ΔTf (kg solvent)]
MM unknown D= 4.30 °C/m (0.09 g)/[3.35 °C (0.00163)] = 70.9 g/mol
The experimental average Kf was calculated to be 4.29, which was pretty close to the actual value of 4.30. The identification of Unknown D was Pentane, and the actual compound was Pentane. However, for Unknowns A and C the experimental molar masses were off by 14 g each. The actual molar mass of ethanol is 46.07, where the experimental one was 160.36. That is mostly due to the hydrogen bonding between ethanol molecules, the strong hydrogen bonding interactions are responsible for the high freezing point, which lead to a higher molar mass.
As you can see supercooling has obviously occurred in graphs 1 and 5. Supercooling is the process of chilling a liquid below its freezing point, without it becoming solid.
The reason why molality was used in the experiment instead of molarity is because molarity depends of volume and volume changes with temperature. A nonpolar solvent would work better with this experiment, because p-xylene is a nonpolar solvent and non-polar molecules will dissolve with non-polar

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