Flexible nanodielectric materials with a high dielectric constant and low dielectric loss have immense potential applications in the modern electronic and electric industry. The use of high aspect ratio fillers is a promising route for achieving high dielectric constant and low loss materials at a low filler volume fraction. However, the poor filler/matrix interfacial adhesion always imposes difficulties in suppressing the dielectric loss of the composites, thus significantly limiting the potential of high aspect ratio fillers in enhancing the dielectric constant of polymer composites. In this study, cable-like structured Ag@C-nanowires with high aspect ratio (>600) were prepared by a facile and environmentally friendly approach. Because …show more content…
Compared to conventional ceramic-based dielectric materials, polymer composites have many advantages such as good flexibility, easy processability, lightweight, and low cost to meet demands for miniaturization of microelectronics that has become a mainstream trend in microelectronic industry in recent years. Thus, flexible polymer composites with a high dielectric constant and low dielectric loss are highly desired and essential for practical application. In recent years, polymer composites with dielectric constant have been prepared by two routes. The more traditional route is introducing high dielectric constant ceramic fillers, such as BaTiO3, Pb(Zr,Ti)O3, and CaCu3Ti4O12 into the polymer matrix. However, the high loading (usually over 50 vol%) of ceramic fillers required for enhancing dielectric constant inevitably raises the issues of inhomogeneity and aggregation of the ceramic fillers in the polymer matrix, deteriorating the characteristics resulting in poor mechanical properties such as high dielectric loss. Furthermore, the dielectric enhancement is usually low. Another route focuses on dispersing conductive fillers such as graphene, carbon nanotubes (CNTs), conductive fibers, and metal particles into the polymer matrix to achieve percolative systems. As the volume fraction of the conductive fillers increases in the vicinity of the percolation threshold, where the conductive fillers connect with each other to form a continuous conducting path, the
PPV, otherwise known as polyphenylene vinylene are electric conductors that processed into tiny films which emit a bright fluorescent yellow light which could potentially be a replacement for LEDS in electronics. PPV is prepared from p-xylene-bis and the addition of acetonitrile-tetrabutylammonium tetrafluoroborate and from there, the product is treated with heat to eliminate diethyl sulfide, HCL, and ethyl sulfide to form the final product, PPV. Similarly, another method, called direct chemical polymerization, formed PPV but it was only in the form of powder which could not be turned into tiny films for commercial use. In lab, we learned that PPV precursor can be synthesized in a one step reaction from p-xylene using NBs. In the reaction with
The stress-strain behaviour of the nanocomposite was found to be independent of the strain rate.
Polymers have been changing the way we live for over 100 years. Their availability and diverse qualities ensure that they are always in high demand, and new polymers are always being discovered. Where does this leave the now commonplace polymers which once were ubiquitous in commerce? Polymers such as polyoxybenzylmethylenglycolanhydride (Bakelite) and polytetrafluoroethylene (PTFE) were first synthesised in 1907 and 1938 respectively, making them old by polymer standards. Although the original polymer applications are now redundant, they have found uses in new areas of society. This dynamic aspect of polymers is due to their unique structure. Polymers are created from many small molecules (or monomers) reacting with each other, and arranging
Carboxyl- or amine-terminated copolymers of butadiene and acrylonitrile (CTBN and ATBN, respectively) are soluble in most liquid epoxies. The end groups react with the epoxy matrix during the curing process and the rubber separates to form discrete particles. Increasing the fracture resistance of epoxies with CBTN or ABTN rubber particles does have deficiencies. Incorporation of a low-Tg component often reduces the glass transition temperature of the composite material [12]. Similarly, incomplete separation of the rubber during cure may plasticize the epoxy network [14, 15]. Both the tensile modulus and yield strength of epoxies may be reduced upon rubber modification [16]. Sultan and McGarry [17] attributed the toughening effect mainly to the crazing of the epoxy matrix. Bascom et al.[12] accredited the high toughness values of CTBN modified epoxy to an increase in the plastic zone size. A rubber stretching and tearing mechanism was proposed by Kunz et al. [18] as the major toughening mechanism for rubber modified plastics (also known as
Pisello et al.[3] investigated for morphology, optical features, thermal characteristics, electrical properties and strain-sensing capability of cement-based composites doped with different carbon nano inclusions, namely MWCNTs, CNFs, CB and GNPs. Author also reported that all carbon nano inclusions are seen to reduce solar reflectance capability, while they produce negligible variations in thermal emittance. Thermal conductivity and diffusivity was increased with Graphene nano platelet and better distribution
However, the absence of plastic deformation does not mean that composites are brittle materials like monolithic ceramics. The heterogeneous nature of composites result in complex failure mechanisms which impart toughness. Fiber-reinforced materials have been found to produce durable, reliable structural components in countless applications. The unique characteristic of composite materials, especially anisotropy, require the use of special design
In this study, we report reports an approach to form an exceptionally high-power lithium-ion capacitor (LIC) using environmentally friendly lithiated silicone oxycarbide (SiOC) material derived from phenyl-rich silicone oil as the anode and activated carbon via KOH activation of snake fruit rinds (SKOH) as the cathode. A battery-type SiOC anode exhibited an incredibly high rate capability in which one third of its initial capacity was maintained even after the discharge current density increased up to 1,600 fold (from 0.05 to 80 A g-1). Moreover, the SKOH cathode demonstrated a massive surface area of 2,638 m2 g-1 promoting a remarkably high capacitance. When coupled to lihtium metal in a cell, the maximum power density of SKOH in LIC was 7.4 × 106 W kg-1 at a current density of 103 W h kg-1 (a loading mass of c.a. 4 mg cm-2). The optimized lithiated SiOC anode and SKOH cathode were paired in an LIC cell, providing a maximum power density of 156,000 W h kg-1 at an energy density of 25 W h kg-1. Moreover, the LIC demonstrates an outstanding cycle retention of 93% after 78,000 cycles.
Polymer composites are assuring in Mechanical and Tribological application due to the possibility of tailoring their properties. These polymer composites have observed in application such as automotive, aerospace and sports equipment industries. When we compared to most metals and unreinforced plastics, this offer a high strength, corrosion resistant, durable and can be fabricated into complex shapes. Major advantages of composite materials are that they can be tailored to meet the specific needs of the structure, determined by reinforcement and matrix in proper way and also these composites have been used in vehicle industries about more than 50%, this is the main reason made to meet the Euro standards and research work as been conducting
Here we report the fabrication of a flexible all carbon field effect transistor (FET) using a low cost, recyclable and biodegradable cellulose paper as both substrate as well as dielectric and pencil graphite as source, drain, channel and gate without using any other expensive, toxic or non-biodegradable materials. The electron and hole mobility’s of FET are observed to be 180 and 200 cm2v-1s-1 respectively which are comparable to the recently reported values of paper FET with polymer dielectric and cellulose composite dielectrics. The FET was utilized as a strain sensor which shows good sensitivity for low strains of both tensile and compressive type. The mobility of the FET increases with increase in compressive strain and decreases with increase in tensile strain. The sensitivity of the FET sensor increases with the increase in the gate voltage.
Polydimethylsiloxane is a silicone based polymer which is commonly used in huge flexible electronics applications due to its unique properties such as optically clear, inert to chemical compounds, and good mechanical strength when compared to the existing flexible substrate. PDMS are the most preferred substarte due to its ease of processing and its biocompatibility (Peterson et al. 2005; Ostuni et al. 2000; De Silva et al.2004; Tan et al. 2003; du Roure et al. 2005). (Abel L. Thangawng et al 2007). The mechanical strength of the PDMS is directly proportional to the amount of cross linking agent integrated into the polymer. Increasing the concentration of cross linker increases the mechanical strength of the PDMS and makes the PDMS to be less
A typical polymer is a very ductile, cheap, and light material that cannot handle high temperatures or electrical conductivity. Polymers are generally used for plastic bags and bottles, crates, toys, and insulation on electrical cables. Electrical conductivity is usually found only in metals because of its small to nonsexist band gap between the filled and empty bands. Electrons are able to move freely between the bands which is the current allowing everything to work. Polymers have a large enough band gap that makes it very difficult for electrons to go between the bands. Large amounts of energy would be needed to force electrons across this gap. However, with the addition
However, designing molds of different soft elastomeric actuators can be costly in industrial manufacturing. For elastomeric actuators, some work is also converted to elastic energy in these actuators, which is wasted as it does not contribute to movement or force generation. Therefore, these actuators may require high input pressures for their operations. Previous research with flexible thermoplastic polyurethane (TPU)-coated fabric [11] has shown that it is a more suitable material due to their flexible but inextensible characteristics. Hence, when actuators are activated, the efficiency of fluid power transmission is increased, thereby requiring a lower pressure for operation. Furthermore, the cost of manufacturing is significantly lower than 3D-printing. As a result, we have chosen to continue working with the TPU-coated nylon fabric, which is more durable than other materials available.
A paper battery is an electrical battery designed to use a spacer fashioned mostly of polyose (the major Constituent of paper). It incorporates nano scale structures to act as high area electrodes to enhance physical phenomenon. additionally to being remarkably skinny, paper batteries ar versatile and atmosphere friendly, permitting integration into a large vary of merchandise. Their functioning is analogous to traditional chemical batteries with the vital distinction that they 're noncorrosive and don 't need intensive housing.
[54-58]. Addition of nanofillers is an efficient method to improve the mechanical properties and the interfacial adhesion as the presence of fiber and the nanoparticle generate a multi-scale, multifunctional reinforcement in the composite system [59]. Multi-scale reinforcement system containing fiber together with nano-scale particles in the matrix or on the fiber surface is found to increase the delamination resistance of the polymer composite
But challenges to make organic materials conducting have already been under way and some success in this direction has been achieved [1]. The charge transfer complex Tetracyanoquinodimethane (TCNQ) – Tetrathiafulvalene (TTF) which has been studied in detail [2] can be regarded as the prototype of conducting organic salts. Recently a compound based on a TCNQ-salt has been used as a solid electrolyte in capacitors [3]. But the lack of reasonable mechanical properties has prevented the widespread applications of these materials. It was a breakthrough, therefore, when Shirakawa found in 1971 that acetylene can be polymerized to give a free standing film with promising mechanical properties [4] and when, somewhat later, MacDiarmid and Heeger [5] showed that polyacetylene becomes conducting by exposing it to oxidizing agents like iodine or arsenpentafluoride (AsF5) and its conductivity can be increased by 13 orders. These findings initiated a lot of fundamental investigations, and gave rise to the development of a new class of materials, which combine the typical properties of plastics with electrical conductivity of metals. In recognition of this pathbreaking discovery Shirakawa, MacDiarmid, and Heeger were jointly awarded the 2000 Nobel Prize in