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In contrast, the PEF-F@MON@Ni recovered after 2000 bending numbers showed nearly no damage in the SEM images (Figures 5g–l). It is surprising that the thin MON coating resulted in a dramatic difference in the conductivity retention of PET-F@MON@Ni in repeated bending compared to that of PET@Ni. Considering the microporosity of MON materials, we suggest that the MON coating may serve as an efficient binder for the more efficient attachment of Ni on the PET platforms. Moreover, we believe that the MON coating can serve as a structural buffer in repeated bending tests owing to its microporous and amorphous nature. These are conventional functions of organic lubricant materials.9

Figure 5. SEM images of (a,d) PET-F@Ni-10, (b,e) …show more content…

(Figures 6h, i). The roles of porous sponge layers can be understood as the relaxing bending strain of the deposited metals and inducing efficient adhesion of metals on polymer films (Figure 6e).

Figure 6. Macroscopic model studies for the roles of MON in PET-F@MON@Ni. Photographs of Cu plate/PET film before bending (a) after 20 bending numbers (b) and Cu plate/polymer sponge/PET film before bending (c) after 20 bending numbers (d). The Cu plate in Figure 6b was broken. Photographs of (f) PET film, (g) Ni/PET film obtained through the electroless Ni deposition, (h) polymer sponge, and (i) Ni/polymer sponge obtained through electroless Ni deposition And (e) Corresponding cartoons.

Next, electrochemical performance of PET-F@Ni-30 and PET-F@MON@Ni-30 as the current collectors for flexible lithium batteries was investigated. Flexible pouch-type lithium-ion batteries were fabricated using a laminated Al film or a transparent polyethylene film as packing materials. The commercial graphite and lithium metal were used as the electrode materials. Graphite (loading amount: 2.1 mg/cm2) was deposited on the current collectors of PET-F@Ni-30 and PET-F@MON@Ni-30. Then, the cells were assembled in a glove box (See detail procedures in the Experimental Section). As shown in Figure 7a, the pouch cells

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