Which of the following species are aromatic or anti-aromatic (assuming n-systems are fully planar)? Circle those that are aromatic Put an X through those that are anti-aromatic Do nothing to the structure otherwise

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter18: Aromaticity
Section: Chapter Questions
Problem 15E
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4.
Which of the following species are aromatic or anti-aromatic (assuming n-systems are fully planar)?
Circle those that are aromatic
Put an X through those that are anti-aromatic
Do nothing to the structure otherwise
5.
Which of the following compounds will have the larger Amax ?
Briefly explain in terms of MO theory and photon energy & basic wave property equations.
6.
For the allyl anion below,
A)
Draw the second resonance structure and show the arrow-pushing needed to get to that structure.
B)
Draw the Valence Bond Theory Orbital Overlap Diagram of the resonance hybrid
C)
Make an Aufbau diagram of the relative energies of the n molecular orbitals, distribute the electrons of the p orbitals to the MO's, and label the
MO's as r, mb, and ri (molecular orbital theory)
D)
Sketch the shapes of the 3 molecular orbitals in part C.
Transcribed Image Text:4. Which of the following species are aromatic or anti-aromatic (assuming n-systems are fully planar)? Circle those that are aromatic Put an X through those that are anti-aromatic Do nothing to the structure otherwise 5. Which of the following compounds will have the larger Amax ? Briefly explain in terms of MO theory and photon energy & basic wave property equations. 6. For the allyl anion below, A) Draw the second resonance structure and show the arrow-pushing needed to get to that structure. B) Draw the Valence Bond Theory Orbital Overlap Diagram of the resonance hybrid C) Make an Aufbau diagram of the relative energies of the n molecular orbitals, distribute the electrons of the p orbitals to the MO's, and label the MO's as r, mb, and ri (molecular orbital theory) D) Sketch the shapes of the 3 molecular orbitals in part C.
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