The reduction of iron(III) oxide (Fe2O3) to pure iron during the first step of steelmaking, 2 Fe2O3(s) 4 Fe(s) + 302 (g) →>> is driven by the high-temperature combustion of coke, a purified form of coal: C(s) + O2(g) CO₂ (g) → Suppose at the temperature of a blast furnace the Gibbs free energies of formation AG of CO2 and Fe2O3 are -442. kJ/mol and -822. kJ/mol, respectively. Calculate the maximum mass of pure iron that can be produced by the combustion of 5700. kg of coke. Round your answer to 2 significant digits. kg ☐ x10

C6H12O6(aq) + 6O2(g) 6CO2(g) + 6H2O(l)ΔH = –2802.7 kJ mol –1a) Write an expression for the equilibrium constant for this reaction.b) At equilibrium, the concentration of the reactants and products are determined as [CO2] = 0.30 M, [O2] = 0.040 M and [C6H12O6] = 0.065 M. Determine the value of the equilibrium constant (Kc) and predict the whether the products or reactants will be favoured at equilibrium.c) Given that the concentrations of the reactants and products at a particular time are [CO2] = 0.65 M, [O2] = 0.020 M and [C6H12O6] = 0.055 M, determine the reaction quotient (Qc). Compare the Kc and Qc values and predict the favoured direction of the reaction.d) Explain the effect on equilibrium of:i) Increasing temperatureii) Increasing pressureiii) Decreasing the concentration of oxygeniv) Increasing the concentration of carbon dioxidev) Adding a catalyst

b) Determine the standard enthalpy change and std. Gibbs free energy change of reaction at 400 k for the reaction СO(g) +2H2(g) — CHОН (g) At 298.15 K, AH.co (0)= -26.41 kcal/mol, AH AG.co (9)= -32.8079 kcal/mol, AG cH,oh(9)= -38.69 kcal/mol, °.CH20H(9)= -48.08 kcal/mol, The standard heat capacity of various components is given by, CO = a + bT + cT² + dT³, where C, is in cal/mol-K and T is in K b x10² с х105 d x10° Соmponent CH3OH а 4.55 2.186 -0.291 -1.92 CO 6.726 0.04 0.1283 -0.5307 H2 6.952 -0.0457 0.09563 -0.2079

2 Zn*2 (aq) +Fe*2 (ag) + 6 CN (ag) = Zn2Fe(CN)6 (5) [znz Fe (CN),] A certain equilibrium reaction has K = 2.8 x 10-13 at 25 °C. What is the change in Gibbs Free Energy (kJ/mole) under these conditions?