6) Draw the chemical structure for the maior metabolite for the following reactions and include the name of the cofactor (if required). a. -CH3 CH3 N-Dealkylation CH3 NO reaction CYP CI Buproprion b. *most common phase II route HO UGT UDPGA GA-0 + UDP N-Dealkylation: Selectivity • N-dealkylation is preferred for short (< 4 carbon) alkyl chain HN–CH3 HN CH3 4 No reaction H3C. NH 3 • A tertiary carbon group is more favored than a secondary carbon * Aromatic para hydroxylation N-dealkylation OH propranolol Have alot of metabolite
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Help me answer 6a based on my note it says no reaction for 4 carbons? how do i count carbons on chain? thank you
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- (a) 2-methyl-2-pentanol Draw the structure of the alkene that was used to prepare the alcohol in highest yield. AAVIL ? ChemDoodleⓇ Which process does this employ? 1. Hg(OAc)2, H₂O; 2. NaBH4 01. BH3; 2. H₂O2, NaOH OsO4, H₂O2 On n [ ]#The reagents below (A-E) are used for the following questions. A H D Br PPh3 :0: H. e B :0: PPh3 (+) E H Which reagents are Wittig reagents? [Select] H Br. :0: Which Wittig reagent would yield a Z alkene when reacted when an aldehyde/ketone? [Select] C Recall the definition/structure of a Wittig reagent. Which reagents could be used to make a Wittig reagent? [Select] Hua U LIIUUSE une correct name tor each structure shown. [ Select) H. CH3 [ Select ] a- OH O CH) HO-E-E- -CH,-CH, CH, [ Select ) V [ Select ] CH-CH,-CH2-C-o-CH, methyl butanoate methyl carboxybutane butyl methanoate CH,-CH-NH-CH, CH, methyl butyl ester H3CN-CH3 'N' [ Select ) [ Select ) H. CH3 -OH [ Select ] CI O CH, HO-C -CH,-CH, [ Select ) ČH, ( Select ) CH,-CH, -CH2-č-o-CH, CH,-CH-NH-CH, V[ Select ] CH, 1,1-dimethylbenzne dimethyl-nitro-benzene H3C CH3 N. 1,1 dimethylcyclohexane N-methyl-2-propanamine [ Sel [ Select ] CH3-CH2-CH2-c-o-CH, CH3-CH-NH-CH; ( Select ] ČH3 H3C., -CH V [ Select ] dimethyl-nitro-benzene 1,1 dimethylcyclohexane N,N - dimethylaniline 1,1-dimethylbenzne NH, [ Select) H,C. NH, [ Select ] CH3-CH2-C-NH - CH,
- Draw a structural formula for the major organic product of the reaction shown below. & CH₂ (oran CH3CH₂O -CuLi 2 ether You do not have to consider stereochemistry. Sn [F ? ChemDoodle H3O +QUESTION 33 Which of the following rate laws accurately describes the rate determining step in an Et elimination of alcohols? OA Rate - Mearbocationproton OH. Rate = kfoxonium lon)[alcohol O cRate kfcarbocation] OD Rate = loxonium lon] OE Rate kcarbocation][water) QUESTION 34 Aqtuieous KMnO4 which is purple, indicatos the presence of alkenos by reacting with them to forn coioriess precipitate and OA. none of the answers OR 12 diols, molybdenum dioxide, orange Or vicinal diols, manganese dioxide. brown O D. glycols, magnesium dioxide, brown OE alkyl chlorides, potasslum hydroxide, yellow O F. geminal diols, manganese dioxide, brown QUESTION 35 five carbon (S)-(+) Carvone was isolated from caraway seeds and belongs to a group of natural compounds called O steralds, one pentane O alkaloids, three, tert-butyl O terpenoids, two, isoprene which contain subunit(s) pentanoids, one, pentane O None of the aboveProvide the missing reactants and reagents. a is bis c is d is e is 11 V < Previous C 0 NHCH3 (R.S)-Methamphetamine
- Provide structures of the reactant/products: a) но. 1. D -MgBr 2. H3O* H 1. LIAIH4 2. H30* b) OH c) H. H* H* acetal OH OH H* H* acetalDraw the organic product(s) of the following reaction. CH3 H3C-C-CEC-H CH3 NaOC2Hs / CH5OH 1 eq. NANH2, NH3(1) CH;CH,CH,CH2-Br H-CEC-H H;C CH-Br H3C 1 eq. NaNH2, NH3() H3C-CEC-HHO HO. OH base CI EIO- C-OEt epichlorohydrin OH NaOEt 2,6-dihydroxy- acetophenone *Na O2C. .CO2 Na* NaOH, H2O II OH Cromolyn sodium Cromolyn sodium, developed during the 1960s, has been used to prevent allergic reactions primarily affecting the lungs, as, for example, exercised- induced emphysema. It is thought to block the release of histamine, which prevents the sequence of events leading to swelling, itching, and constriction of bronchial tubes. v Cromolyn sodium is synthesized in the above series of steps. rch 31% 11:24 P 4/20/20-
- What is the intermediate before the final product of the following reactions? ii NaOH H* heat O a. Na Ob. OH OH Od. Na* он e. Of.What is the major product of the following reaction? NH* CrO3CI" HO. CH2C1, O a. butanone O b. butanoic acid O c. but-1-ene O d. none of the other answers e. butanalOH Cl what reagent and type of reaction has happened? (A HCI, H2O ; halohydrin formation (B C12, H20 ; halohydrin formation c) 2HCI ; hydrohalogenation D C12, H20 ; halogenation