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Give some examples of secondary standard solutions, and give the reason
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- Use the following data to calculate the enthalpy of solution of sodium perchlorate, NaClO4: fH(s)=382.9kJ/mol and fH(aq,1m)=369.5kJ/mol1. Calcium in a sample solution is determined by atomic absorption spectroscopy (AAS). A stock solution of calcium is prepared by dissolving 1.834 g CaCl, 2H,0 in water and diluting to 1 litre. From this stock solution, the second stock solution is prepared by the dilution factor of 10. Three standard solutions of calcium are prepared from the second stock solution with the following dilution factor: 20 (first standard solution), 10 (second standard solution) and 5 (third standard solution). A blank solution is prepared as well. Absorbance signals of AAS are as follows: 1.5 (blank solution), 10.6 (first standard solution), 20.1 (second standard solution), 38.5 (third standard solution), 29.6 (sample solution). (Molar mass; Ca = 40.00 g mol-, CI = 35.45 g mol-, 0 = 16.00 g mol-', H = 1.00 g mol-1) a. Construct ONE (1) plot that could be used to represent the calibration curve. b. From the plot of Q1a, determine the amount of calcium in parts per million.1. A sample of pure sodium oxalate, Na2C2O4 , weighing 0.2856 g is dissolved in water, sulfuric acid is added, and the solution titrated at 70°C , requiring 45.12 mL of a KMNO4 solution. The end point is overrun and back-titration is carried out with 1.74 mL of a 0.1032 N solution of oxalic acid. Calculate the normality of the KMNO4 solution. Hint: A redox reaction is involed between oxalate and permanganate. Look at the changes in oxidation state by determining the balanced redox reaction: 5C20,2 + + 2MN2+ 2 Mn04 + 10H* → 10CO2 + 8H20
- Calculate the following: The vapor pressure of benezene, C6H6 at 25C in an ideal solution containing 1.66 mol of benezene and 0.313 of toulene. The vapor pressure of pure benezene is 96.0 torr.Q/ Mohr's method uses the potassium chromate indicator and this indicator makes the equivalent point not identical to the end point. A sample weighing 5.592 g of BaCl2 is dissolved in 500 mL of water. Calculate the percentage of chloride in the sample when 25 mL of the sample is titrated and requires 33.47 mL of 0.1098 N AGNO. SOLUTION:Caculate the volume (mL) of 1.0 M potassium carbonate (K₂CO₃) needed to prepare 5.0g of the COPPER pigment. This is where the balanced chemical equation come in. You should be able to relate the moles of pigment to the moles of K₂CO₃, and from that calculate the volume of 1.0 M K₂CO₃ solution needed. Please report your value as XX.X mL (one deicmal point and no units).
- A chemist receive different mixtures for analysis with the statement that it contain NaOH, NaHCO3 , Na2CO3 or compatible mixtures of these substances together with the inert material. From the data given, identify the respective materials and calculate the percentage of each component. 1.000g samples and 0.2500 N HCl were used in all cases. Sample 1 With phenolphthalein as the indicator, 24.32 ml of HCl was used. A duplicate sample required 48.64 ml HCl using methyl orange as the indicator. Sample 2. With phenolphthalein as the indicator it uses 28.2 ml of HCl to make it colorless and added with methyl orange indicator and uses 11.3 ml of HCl to reach the end point.A buffer is prepared using lactic acid (HLac) and sodium lactate (NaLac). 0.300 dm3 of the 0.500 mol·dm–3 HLac solution is mixed with 0.300 dm3 of the 0.300 mol·dm–3 NaLac solution to prepare the buffer. Ka for lactic acid (HLac) is 1.4 x 10–4 Calculate the pH of the sodium lactate solution before it is mixed with the HLac to form the buffer.(c) What is a standard solution? What piece of glassware is used to prepare a standard solution and describe how a standard solution of sodium carbonate may be prepared in the laboratory?
- A buffer is prepared using lactic acid (HLac) and sodium lactate (NaLac). 0.300 dm3 of the 0.500 mol·dm–3 HLac solution is mixed with 0.300 dm3 of the 0.300 mol·dm–3 NaLac solution to prepare the buffer. Ka for lactic acid (HLac) is 1.4 x 10-4 a) Calculate the pH of the lactic acid before it is mixed with the NaLac to form the buffer. b) Calculate the pH of the sodium lactate solution before it is mixed with the HLac to form the buffer. c) Calculate the pH of the buffer solution.Each row of the table below describes an aqueous solution at 25 °C. The second column of the table shows the initial components of the solution. • Use the checkboxes in the third column to explain the type of the initial solution. The fourth column describes a change in the solution. • Use the fifth column to predict how the change in the solution will change its pH. solution initial comp ents A B H₂O H₂O, HC104 H₂O, HCIO4 H₂O initial type (check all that apply) acidic basic neutral acidic basic neutral acidic basic neutral acidic basic neutral 0 0 00 000 00 change add HCl add K CIO4 add KOH add Na Cl effect of change on pH (check one) pH higher pH lower pH the same pH higher pH lower pH the same pH higher pH lower pH the same pH higher pH lower pH the sameA buffer is prepared using lactic acid (HLac) and sodium lactate (NaLac). 0.300 dm3 of the 0.500 mol·dm–3 HLac solution is mixed with 0.300 dm3 of the 0.300 mol·dm–3 NaLac solution to prepare the buffer. Ka for lactic acid (HLac) is 1.4 x 10–4. What will the pH of the above solution be after 5.0 cm3 of 0.200 mol·dm–3 NaOH has been added to only 100.0 cm3 of this buffer?