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- Explain the importance of determining the partition coefficient during liquid-liquid extraction in food industry.The partition coefficient K for a compound between dichloromethane and water is determined to be 56 : 1 (K=56). If 10.0 mg of the compound is dissolved in 50.0 mL of water and this solution extracted with 25.0 mL of dichloromethane, how many mg of the compound will remain in the water layer following the extraction procedure? Show you calculationsWhat is the strength of the ionic interactions between an ion with 1 positive charges and an ion with 2 negative charges, when the distance between them is 32.5 nanometers and the solvent is water, at 25 oC with a dielectric constant of 78.5? Calculate answer to 7 decimal places.specify units in the answer. Thank you very much for your assistance.
- Arrange the following compounds in order of decreasing ease of elution from a column of silica gel: (a) 2-octanol; (b) 1,3-dichlorobenzene; (c) tert-butylcyclo hexane; (d) benzoic acid.What is the Madelung constant for MgO (rock salt) structure? Include only the first 3 terms. Give your answer to 3 significant figures.(c) State the assumptions and limitations of Langmuir's Adsorption equation for a gas on solid.
- What measures can be taken to decrease relative supersaturation during precipitation? Explain.An experimental method of determining solubility parameters of polymers involves taking lightly crosslinked (network) samples of the polymers in question and immersing them in different solvents whose solubility parameters are known. Explain the rationale behind this method.What is the strength of the ionic interactions between an ion with 1 positive charges and an ion with 2 negative charges, when the distance between them is 19.4 nanometers and the solvent is water, at 25 oC with a dielectric constant of 78.5?
- Do the conclusion to polymer molecular weight determination by dilute solution viscosity measurement.(a) What is the difference between the states of phase equilibrium and metastability? (b) Explain with the aid of neatly drawn binary phase diagrams the following terms? i. Isormophous phase diagram ii. Eutectic Isotherm iii. Peritectic pointFind the thermodynamic dissociation constant of cyanoacetic acid, NCCH2CO2H, if the apparent (or analytical) constant is 3.3710-3 and ionic strength is 0.25.