For the reaction shown below, draw the structure(s) of the major product(s) expected. Do not draw duplicate structures of the same mc products. (Do this on a piece of paper, then scan into PDF file and upload.) (1) O3 "CH3 (2) Zn, aqueous acid
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- 5a) Draw the product(s) of the reaction shown below. Additionally, identify the nucleophile, electrophile and leaving group.1) LIAIH4 2) H20 14. MgBr 15. Please devise syntheses of the product compounds below from their respective starting material(s) on the left. Each of the synthesis will require multiple steps. If you can't think of a reagent for a particular reaction, just write the product and continue from that compound. ( но. 16. 17.On a sheet of paper, answer the following questions. Make sure to put your name at the top of the paper first. When complete, take a photo, send, attach, and save the question. (a) Draw the major organic product of the following reaction: O3 H20, Zn (b) Propose a mechanism for the reaction shown here, which takes place under conditions that favor an Br SN1 reaction. Br (c) You are a chemistry company's latest chemistry recruit and your first job is to prepare 2- methylcyclohexanol. The one key starting material you have been given is methylcyclohexane. Draw a scheme to take you from the starting material to the product outlining the reagents you would use for each step as well as the key organic product(s) formed from each step. [Note: You do not need to show mechanisms for any steps] ОН methylcyclohexane [STARTING MATERIAL] 2-methylcyclohexanol [PRODUCT]
- 9) Suppose I want to perform a simple substitution reaction, replacing the OH with a Cl in the following compound. Which of the following reagents works best? Explain (and that means explain why the wrong answers are wrong as well as why the right answer is right). Option A: Addition of HBr Option B: Addition of SOC12/pyridine Option C: Addition of SOCl2 only OH ? J12. Show the organic product formed when methyl propanoate is reacted with lithium diisopropyl amide, then methyl ethanoate is slowly added to the mixture. The mixture is neutralized with aqueous acid to obtain a neutral product. (A) Show the steps in the mechanism as reactant is converted to final product. show appropriate arrow pushing and any charges. (B) Draw a box around the final product.Organic chemistry student Everett has set up two separate electrophilic addition reactions with 2-butyne (shown below). In reaction (i) the alkyne is treated with 1 equivalent of HBr, which successful provides (Z)-2-bromo-2-butene. In reaction (ii) the alkyne is subjected to a two-step hydroboroation/oxidation sequence. Interestingly, Everett’s second reaction fails to provide the desired methyl ketone and instead has provided butan-2,3-diol. (a) Provide the structure of intermediate X form the first step of reaction (ii). (b) Briefly explain (use structures if necessary) why reaction (i) provided an alkene where as reaction (ii) provided an alkane when only 1 equivalent of the electrophile was used in each reaction.
- (d) Consider the following catalyzed and non-catalyzed pathways of a substitution reaction of bromoethane. Draw an energy diagram for each of the following reactions (label all axes and include reactants, intermediates (if any) and products). CH3CH₂Br + HO CH³CH₂OH + B (non-catalyzed) ное CH3CH₂Br + CH3CH₂OH + 1 (catalyzed) CH3CH₂ + BrA student wants to choose the best solvent for organometallic compounds such as Grignard reagents. Based on the three solvents below, explain which is the best solvent for Grignard reagents. (You must also explain why the others are not suitable). (c) `O-H ether ethanol ethyl acetatePredict the major product formed when the compound shown below undergoes a reaction with CH3OH under acidic conditions. Interactive 3D display mode H3C- Draw the molecule on the canvas by choosing buttons from the Tools (for bonds), Atoms, and Advanced Template toolbars. The single bond is active by default.
- On a scrap piece of paper, draw a curved arrow mechanism for the following reaction. Once you have determined the major product, draw it in the space provided below. H 1) t-BuNH₂, HCI(cat.) 2) LDA, THF, -78 °C 3) n-BUCHO 4) NH4CI, H₂ODecide whether the reaction below will proceed via an SN1 or SN2 mechanism. (b) Draw structural formula from the major organic product only4. Synthesis Using the carbon-containing starting material(s), propose a synthesis by drawing structures for all intermediates. The carbon atoms in the product must originate from the starting material(s) (or a carbene/carbenoid or CO₂), but you may use as many equivalents of each starting material as you would like, and any reagent/reaction you know. (note: no mechanisms are required). (a) || محمد b