For the reaction below, on the assumption that nucleophilic attack is extremely slow, which of the following products would you expect to be the major product? Choose only one. [HBr] H₂O 10°C Safrole. Antifeedant produced by sassafras plants d) a) Br Br g) Br h) Br b) DY Br c) Br f) Br Br 201 Br
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- Use the reaction given below to answer the following questions. A CH₂OH B H₂O+ C + CH3NH3* D a) What are the approximate pKas of compounds A and B? b) The reaction given above is irreversible. Give a detailed explanation of the reaction and reaction mechanism. Your explanation should indicate your knowledge of the reactivity of carboxylic acid derivatives.Rank the following nucleophiles in order from slowest SN2 reaction rate to fastest if DMSO is the solvent. ОН PH SH A B D EDraw the favored product(s) of the following reactions (organic chemistry)
- Which of the following is NOT a good nucleophile for SN1 reactions? 1) NaOCH3 2) CH3OH 3) CH3CH2OH 4) H2OIn the presence of a nucleophile, which of the following will most likely undergo conjugate addition? B) OCH3 A) D) O A ов C ODConsider the following reactants: Br Would elimination take place at a significant rate between these reactants? If you said elimination would take place, draw the major products in the upper drawing area. If you said elimination would take place, also draw the complete mechanism for one of the major products in the lower drawing area. If there is more than one major product, you may draw the mechanism that leads to any of them. Major Products: Oyes по
- Determine whether the following reaction is likely to proceed by an E1 or E2 mechanism. CH;CH;OH Br E1 None E2Q10. For each of the following reactions (a-b), predict whether the substitution is more likely to occur following an Sn1 or Sn2 mechanism; explain your reasoning. Draw the products of each nucleophilic substitution paying particular attention to the stereochemistry of carbon 1. а) Br CH3 MeOH H3C b) Br NaOH DMF* H3C *N,N-dimethylformamideList the following in increasing order of nucleophilic strength. CH3COO-, H2O, CH3O-, OH-, CH3CH20-
- Rank the set of compounds in order of reactivity (fastest to slowest) in a nucleophilic addition-elimination reaction with a nucleophile such as CH3NH2.Explain why the following are NOT the products you would predict for a one-step nucleophilic substitution reaction, and draw the correct product/s. (Note: Nat is a spectator ion.) H3C H3C Na Na но CH2CH3 CH2CH3Choose all the nucleophiles OH- H3O+ NH4+ CH3OH (CH3)3CLi CH3CH2CH3 NaNH2 CH3SNa