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- ▬▬▬▬▬▬▬ 31 Give the organic product: A. B. x OH OH -OH + Cr₂O²/ C. X H₂O, heat D. XX° E. No Reactionно. OH HO OH HOOC COOH Reagents 2 NaNH2 CH212, Zn(Cu) a. g. b. 2 HCHO then HCI h. RCO3H C. H2, Pt i. H,CrO4 d. H2, Lindlar's catalyst е. Na, NH3 (liq) f. then HCI Select reagents from the table to carry out each step of this conversion of acetylene into a dioic acid. If more than one reagent is necessary for a particular step.enter the letters in the order that you wish to use the reagents without punctuation (i.e. 'bc'). If the reaction has only three steps, leave step 4 blank. Step 1: Step 2: Step 3: Step 4:21. The reaction scheme for the preparation of Z starting from benzene is as follows: CH,CI/AICI; KMNO. H" ClyAICl; C6H6 What is Z? A. CI В. C. D. CH,COCI COOH CH,COOH CICH B. D 27
- Reagents m. 2 equivalents of NaNH2 H2, Lindlar's catalyst Na / NH3 p. H2SO4, HgSO4 q. (sia)2BH then H2O2, NaOH 1 equivalent of NaNH2 a. HCI b. HBr n. c. H20, H2SO4 d. Br2 0. n Cl2 е. H2, Pd g. Br2, H20 h. Cl2, H2O f. r. compound a Os04 then NaHSO3 j. Hg(OAc)2, H20 then NABH4 k. BH3 then H2O2, NaOH Oz then (CH3)2S i. compound b I. The above synthesis was designed using the Organic Chemistry Roadmaps in the appendix of your textbook. In this synthesis, reagents from the table (shown in blue) are used to carry out the indicated reactions. In the box below, draw the structure of compound b. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • Consider E/Z stereochemistry of alkenes. • If more than one structure fits the description, draw them all. • If a compound is formed more than once, add another sketcher and draw it again. • If the reaction produces a racemic mixture, draw both stereoisomers. Separate structures with + signs from the drop-down menu.What is the product of the following reaction? 1. B2Н6. THF 2. NaOH, H2O2 он HO С. А. В. D.What is the product for the following reaction? NO₂ a. b. d. NO₂ No reaction NO₂ O § AICI3 NO₂ f NO₂ NO₂ CI X
- Reagents A. Cu(SO4)2, NaHCO3, Na-citrate B. concentrated HCI, orcinol, FeCl3 C. Alkyl chloride, AlCl3 D. NH₂OH, alcoholic HCl, alcoholic KOH, FeCl 3 E. Dilute KMnO4 F. NaOH, KI, 1₂ G. FeCl3 Observation H. blue-green solution 1. Formation of purple-colored solution J. Decolorization of purple solution and formation of brown precipitate K. Formation of yellow precipitate L. Formation of a colored complex M. Appearance of a brick red precipitate N. Change in color of the crystal; warm test tube Given the following reagents and tests above, what could best differentiate the two compounds below? Provide also the letter of the expected experimental observation and state which of the two would give that result. OH OH OHReagents A. Cu(SO4)2, NaHCO3, Na-citrate B. concentrated HCI, orcinol, FeCl3 C. Alkyl chloride, AlCl3 D. NH₂OH, alcoholic HCl, alcoholic KOH, FeCl 3 E. Dilute KMnO4 F. NaOH, KI, 1₂ G. FeCl3 Observation H. blue-green solution 1. Formation of purple-colored solution J. Decolorization of purple solution and formation of brown precipitate K. Formation of yellow precipitate L. Formation of a colored complex M. Appearance of a brick red precipitate N. Change in color of the crystal; warm test tube Given the following reagents and tests above, what could best differentiate the two compounds below? Provide also the letter of the expected experimental observation and state which of the two would give that result. O1. What is the major organic product obtained from the following reaction? (1pt) 1 O-tBu 2 KOTBU Br O-tBu 3 Br O-tBu a. b. с. d. 1234