Either the reactant (X) or the major organic product is missing from the equation below. Draw the missing compound. 0 CH2 CH₂CCH₂CCH2 CH3CCH2CCH2CH3 Pd/C + H2 (1 equivalent) • You do not have to consider stereochemistry. . In the case of a missing reactant, there may be more than one answer. If so, draw all possible reactants in separate windows. . Separate structures with + signs from the drop-down menu. + n D
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- Substitution and elimination: predict the product Maximum allowed tries per question: Unlimited (7) Draw the major organic product of the reaction. Follow this procedure: determine whether the reaction conditions are acidic or basic; identify the most nucleophilic/basic atom, the electrophilic atom, and the leaving group; predict whether elimination or substitution will occur; and then draw the product. Indicate the stereochemistry at every stereocenter with a single wedged (up), hashed (down), or wavy (a mixture of up and down; either) bond. Launch MarvinJSTM viewer or click image to copy source CH3 H3C EtONa EtOH BrEither the reactant (X) or the major organic product is missing from the equation below. Draw the missing compound. [Review Topics] [References) X + H2 Pd/C CH3 CH3 • You do not have to consider stereochemistry. • In the case of a missing reactant, there may be more than one answer. If so, draw all possible reactants in separate windows. • Separate structures with + signs from the drop-down menu. C ChemDoodle (Previous Next Save and Exit etv 29 MacBook Air DII DD 888 11 F9 F10 F7 FB F6 E4 F5 F3 %23 $ & de 4 6. 7 { Y U E J K L D + I| .. .- * C0 R7oar tavorite distributel berzene derivatives You must have 2 molecules, Please Substituent Draw two of make ( deactivators) and the other substituent an one electron with drawin grave an electron donanting group (actiuators) Une of these molecules must have substituents meta tu each other. The other molecule must must Your molecule have substituents para to each other for each molecule respectively. substituent donathng One electron withd raving electron Substituent anel one contain
- Complete the following transformations with the missing indicated reactant/conditions/product. Be clear in your drawing of regiochemistry and stereochemistry, when applicable. Please upload your work in a pdf, jpeg, or png file format. 1. CHCOH 2. ETOH, H* ? ? 1.03 2. Zn. H₂O EmConsider the reaction and answer the questions that follow. CH-CH2- CH2-I • CH,S° CH3- CH2- CH2-S– CH; + CH3-CH= CH2 Product A Product B O Explain which type or types of mechanisms (Sw1, SN2, E1, and E2) are applicable to this reaction. [") How can you increase the percentage of Product A? [ui) How can you obtain Product B as almost the only product? A. [i] SN2 & E2 [ii] Use better nucleophile [iii Use a non-nucleophilic base B. [i] SN2 & E2 [ii] Use higher Temperature [iii] Use a non- nucleophilic base C. [i] SN2 & E2 [ii] Use lower Temperature [iii] Use a non-nucleophilic base D. [i] SN1 & E1 [ii] Use lower Temperature [iii] Use a non-nucleophilic baseM M M M M M M M Creq M M M M 0 Draw a structural formula for the missing organic product in the reaction below. + CHỊCH, NHCH, CH3 − ? + ● CH₂CH₂CH₂CH₂CH₂COCCH₂CH₂CH₂CH₂CH3 *** [Review Topics] [References] Use the References to access important values if needed for this question. • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. Do not include lone pairs in your answer. They will not be considered in the grading. 8 CH4 COWLv2 | Online teaching and learning resource from Cengage Learning [ ] در ChemDoodle CH₂CH₂CH₂CH₂CH₂CH CH₂CH₂CH Previous Next Save and Exit
- Draw the structure of the principal organic product that forms in each of the following reactions. Specify stereochemistry where appropriate please [30] 5. Draw the structure of the principal organic product that forms in each of the following reactions. Specify stereochemistry where appropriate. a) b) PraSiO CH3 C N OOH (mCPBA) CH₂Cl₂/-20°C O (EtO)2PCH₂COCH3 (1 eq) LICI/CHICN 4app.101edu.co Draw the major product of this reaction. Ignore inorganic byproducts. Assume that the water side product is continuously removed to drive the reaction toward products. esc F1 CH3CH2CH2OH H2SO4 (cat), heat ☀ F2 80 F3 OH a F4 W Q F5 Atoms and P Draw or ta MacBook A C F6While we are at it, let's do the same thing for the second step of the mechanism. Again, what is happening with the arrows circled in red below? Cys157 Cys157 Cys157 His296 His296 His296 OH OH HN, HN HN -CO2 CH2 Asn329 Asn329 Asn329- Cys157 His296 OH OH HNNH HyC. H,C. Asn329- O deprotonation of the conjugate acid form of imidazole, followed by general base assistance in decarboxylation O nucleophilic addition of the cysteine side chain to imidazole O decarboxylation coupled with the generation of molecular hydrogen (H2) O general acid catalyzed isomerization n covalent attachment of the substrate to the enzyme
- Draw the major organic product of the reaction shown below. pyridinium chlorochromate (PCC) -CH2OH CH2CI2 • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. opy aste [F ChemDoodleUse the E2 mechanism to explain why when I is mixed with sodium ethoxide (NaOEt) in ethanol, the major product is III, but when II is mixed with sodium ethoxide in ethanol, the major product is IV. H3C CH3 H3C CH3 ..CI CI CH3 I CH3 || H3C. CH3 H3C CH3 E ||| CH3 CH3 IV SANSubstitution and elimination: predict the product Maximum allowed tries per question: Unlimited (5) Draw the major organic product of the reaction. Follow this procedure: determine whether the reaction conditions are acidic or basic; identify the most nucleophilic/basic atom, the electrophilic atom, and the leaving group; predict whether elimination or substitution will occur; and then draw the product. Indicate the stereochemistry at every stereocenter with a single wedged (up), hashed (down), or wavy (a mixture of up and down; either) bond. Launch MarvinJSTM viewer or click image to copy source CI benzene A