Draw the major product of this elimination. Consider regiochemistry and stereochemistry. Ignore byproducts. CI CH3ONA, CH3OH heat Draw Major Elimination Product
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- Predict the reaction outcome showing and explaining proper Transition States. 6. Draw the major product with proper stereochemistry and explanation showing the correct approach of nucleophile. a) b) OMe NBn2 EtMgBr then H* Ph OLi H CHO Me then H* R Li d) SMe H ZnBH4 ? Ph. -N. ? then H+ R f) OSiMe₂Ph NaBH4 OH O NaHB(OAc) ? OSIMe2Ph is larger than Ethyl g) h) R = Et MeLi then H+ MeLi then H* R = OH and and ? R R = CO₂Me R = CO₂Me R R1. Draw the intermediates A-C for reactions a and b. Please show the appropriate stereochemistry where necessary. RO hv .. RQ CO₂Me MO,C. Anti-tumour agent Coriolin co₂Me barrelenePlastic photochromic sunglasses are based on the following reversible rearrangement of a dye inside the lenses that occurs when the lenses are exposed to sunlight. The original dye absorbs UV light but not visible light and is thus colorless, while the rearrangement product absorbs visible light and is thus darkened. (a) Show the mechanism of the rearrangement. (b) Why does the rearrangement product absorb at a longer wavelength (visible light) than the original dye (UV)?
- Determine the mechanism of nucleophilic substitution of each reaction and draw the products, including stereochemistr CH₂CH3 CI Br + CN d. + CH3COOH a. acetone + -OCH3 e. DMF f. b. C. ||||| a ||||| Br H Br CH2CH2CH3 + CH3OH DMSO H CH3 CI Br + OCH₂CH3 + CH3CH₂OHWhich conditions will produce the target product in the highest yield? O A) 1. BH3; 2. H₂O₂, NaOH, H₂O B) 1. OsO; 2. S(CH3)2 C) 1. Hg(OAc)₂, H₂O; 2. NaBH4 D) H₂SO4, H₂O A ? B OH racemic mixtureew fopics] Draw the major organic product of the reaction shown below. H2SO4 HO, • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. C opy aste [F ChemDoodle
- 4) Give the correct product with the correct stereochemistry. Me Me 5) Give the major product. hv HCI OC5. Provide a base to prepare the following major products for each of the following E2 reactions. Explain. Chemistr S Br b) @ OT “Chérsistry SE Chemistry SkipsDraw the curved arrow notation and predict the products when one equivalent of methoxide in DMSO a: rcom ten:perature is sdced to S-brome-1. 1odepentane. Part 1 ht See Periodic Table O See Hint DMSO Draw the curved arrow notation. Part 2 Select the major byproduct. Chooso one: O A, I- O B. HI O C. CH:OH O D Er. O E. Her
- Mclent eynthesis tor the following compounds trom benaen OF Br Provide the complete arrow pushing mechanism and the major product for the follc Major Product 8) reaction. H,SO, он но15. a. Predict the major product for each of the following reactions. Include stereochemistry when appropriate. If more than one product forms indicate Major, minor, and very minor as applicable. میں Me Me Me!!!.. A Br B "Et Br Et Br Et KO'Bu, DMSO KO'Bu, DMSO KO'Bu, DMSO b. Rank the reactions according to increasing rate:Draw the major organic product of the reaction shown below. O Ca OH **** + HBr • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. - ] Jn [1 ChemDoodleⓇ 5b