Construct an MO diagram for staggered ferrocene 1. What is the oxidation state of Fe in ferrocene?2. How many d-electrons are counted on Fe?3. Be sure to show the MO diagram for the pi system of C5H5–. Be sure to show which are bonding and which are non-bonding pi orbitals.4. The appropriate valence orbitals on the metal are the 4s, 4p, and 3d orbitals. Classify any bonding intersections with the pi system of the ligands as sigma, pi, or delta (you need only worry about symmetry arguments).5. Be sure to show the crystal field d-orbital splitting in your diagram (and include the correct number of d electrons!)
Construct an MO diagram for staggered ferrocene 1. What is the oxidation state of Fe in ferrocene?2. How many d-electrons are counted on Fe?3. Be sure to show the MO diagram for the pi system of C5H5–. Be sure to show which are bonding and which are non-bonding pi orbitals.4. The appropriate valence orbitals on the metal are the 4s, 4p, and 3d orbitals. Classify any bonding intersections with the pi system of the ligands as sigma, pi, or delta (you need only worry about symmetry arguments).5. Be sure to show the crystal field d-orbital splitting in your diagram (and include the correct number of d electrons!)
Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter7: The Structure Of Atoms And Periodic Trends
Section7.6: Periodic Trends And Chemical Properties
Problem 1.3ACP
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Construct an MO diagram for staggered ferrocene
1. What is the oxidation state of Fe in ferrocene?
2. How many d-electrons are counted on Fe?
3. Be sure to show the MO diagram for the pi system of C5H5–. Be sure to show which are bonding and which are non-bonding pi orbitals.
4. The appropriate valence orbitals on the metal are the 4s, 4p, and 3d orbitals. Classify any bonding intersections with the pi system of the ligands as sigma, pi, or delta (you need only worry about symmetry arguments).
5. Be sure to show the crystal field d-orbital splitting in your diagram (and include the correct number of d electrons!)
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