Consider the SN2 reaction between 1-bromo-2-methylpropane and methoxide. Add curved arrows to the starting materials to indicate the flow of electrons. Draw the product species to show the balanced equation, including nonbonding electrons and formal charges. H₂ H3C H C - Br: + :0-CH3 product CH3 Draw curved arrows. Select Draw Templates More // C Br 0 H₂C EC CH₁ - Br Draw the products. The bromide ion has been drawn for you. Erase : 0— CH, Select Draw Templates More ///// C Br 0 Erase
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- 3. For questions "A"- "C", complete the following reaction schemes (no mechanisms required). Show all reagents used in the order of application. th A) 6 B) ||| Ins HO HO4. Use the reactant below to perform two separate reactions. Give the mechanism(s) and product(s) for each reaction. Show stereochemistry and be clear in your work. Use chair form. KOEt, EtOH t-Bu |||| H3O+Organic chem 2 For the reaction: HCI 40° C a Draw the structure(s) of the major product(s) from addition of 1 equivalent of HX to the conjugated diene. • Only give structures deriving from the most stable carbocation. . You do not have to consider stereochemistry. ⚫ Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. อ २ [] ChemDoodle ་
- Step 3: Complete the structure and add curved arrows. Select Draw Templates More / 3 H C acetal 2° gem-diol hemiacetal O 1° gem-diol H : 0 H H Erase 2 Q Select the choice that best describes the final structure. 11 Step 4: Complete the structure. Select Draw Templates More G C H O H 1 H H Erase Q 2 QoutinerlegacyUrl=%252Fwe Your answers are saved automatically. Remaining Time: 2 hours, 35 minutes, 42 seconds. * Question Completion Status: A Moving to another question will save this response. Question 2 The reaction of sodium ethoxide with iodoethane to form diethyl ether is classified as: O an electrophilic substitution O a nucleophilic substitution O a radical substitution O an electrophilic addition A Moving to another question will save this response. O Type here to search a. 立Complete the mechanism for the reaction of excess ammonia with 4-chlorobut-1-ene by adding any missing atoms, bonds, charges, nonbonding electrons, and curved arrows. Step 1: Add curved arrows. Select Draw Templates More / → H- C :N — H H - H N Cl NH₂ Erase + 2 Q ↑ Step 2: Complete the structure and add curved arrows. Select Draw Templates More / |||||| C Cl Erase : NH, Q2 Q ↑
- ow the mechanism for the following reaction conducted at -5 °C in CC14: cyclohexene + bromine yields a dibromocyclohexane Draw structures - including charges and electrons - and add curved arrows. Details count. Step 1 Add three curved arrows to the first step. Draw the step 1 products: 1 organic species; 1 inorganic species. Step 2 • Reproduce the step 1 products. Add two curved arrows to show the bromide ion reacting with the organic species. Draw the final product. 1L o ↑ MapH но. но HO Ethylene oxide is the starting material for the synthesis of 1,4-dioxepane. Draw curved arrows to show the movement ofelectrons in this step of the reaction mechanism. Arrow-pushing Instractions HO+ но H,ö: HO: :o: :o: I-Construct a three-step synthesis of 1-bromopropane from propane by dragging the appropriate formulas into the bins. Note that each bin willl hold only one item, and not all of the given reagents or structures will be used. Reactant Reagent 1 Step 1 Product Reagent 2 Step 2 Product Reagent 3 Final Product (1-bromopropane) (propane) Br2 Br2 (CH)3CO K HBr ROOR HBr NBS ROOR HaC Нас Нас, Нас Нас НаС. hv CH2 CH2 CH Нс CH-Br CH-Br CH Нас Нас, нC Нас НаС Br Br Br
- Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. · Select to Add Arrows I Brh H Br. H 0. H Br2 H₂O Br2 = H₂O Br: O Br HOH Select to Add Arrows I Br2 H₂O Br H. Br: OH Select to Add Arrows IDraw the alkyl bromide for reaction 2. Select Draw Rings More Erase | 7 | | H Br Reagents Carboxylic Acid Product 1. Diethyl malonate, NaOC2H5, C2H5OH 2. NaOH, H2O 3. H3O*, heat ОН Draw the alkyl bromide for reaction 3.Dtermine the reagents that can accomplish the rxn CH2OH (1) Reagent ? (2) Reagent ? C9H1202 (4) Reagent ? (3) H+ a. (1) SOC12 (2) 1-propanol; (4) PCC/pyridine b. (1) NaH, (2) acetone, (4) NABH4 c. (1) NaH, (2) epoxide (4) PCC/pyridine d. (1) Jones reagent, (2) NaH, (4) epoxide