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The equation to calculate for molar absorptivity (ε) is ε = A/(bc) where A is absorbance (unitless), b is path length in cm, and c is concentration in M. Suppose you have a solution with concentration of 2.9 ± 0.25 M, a path length of 1 ± 0.1 cm, and an absorbance of 0.4629 ± 0.0006. What is the uncertainty or error for the molar absorptivity?
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- To determine the molar concentration of a metal ion in a solution of unknown concentration, a student fırst made five standard solutions that contain the metal ion of interest and measured the absorbance of each solution in a spectrophotometer at its Amax- A calibration curve was obtained that had an equation of y = 5.747 x + 0.013 Next, the student pipetted 15.0 mL of the initial solution of unknown concentration into a 100.0 mL volumetric flask, and filled the flask with deionized water to the line. The absorbance of this final diluted solution was found to be A = 0.226 at Amax. The color of the original and diluted solution was blue. What is the molarity of the original solution, as well as an approximate Amax for this metal ion? 2max = 599 nm and concentration is 0.247 M Amax 457 nm and concentration is 0.247 M %3D 2 max = 457 nm and concentration is 0.0371 M 1 max 599 nm and concentration is 0.0371 M Amax = 599 nm and concentration is 0.00557 MA student prepared four standard solutions of (NH4)2Fe(SO4)2 and measured their absorbance at 505 nm. She created a calibration plot with the best-fit line of y = 9372 x + 0.0539. She measured the absorbance of her diluted unknown sample solution as (4.69x10^-1) nm. If she prepared her diluted sample solution by diluting 10.00 mL of the original solution to a total volume of 50.00 mL with deionized water, what is the concentration of Fe2+ in her original solution? Answer in units of M. Note: Your answer is assumed to be reduced to the highest power possible.After determining the absorbance of several standards of known concentration, the trend line for a calibration curve plotting absorbance (y-axis) against concentration (uM, x-axis) is determined to be y=4.244x+0.0000. The absorbance of a solution of unknown concentration is determined to be 0.604. Calculate the concentration of the unknown solution in microM. Give answer to 3 decimal places
- After determining the absorbance of several standards of known concentration, the trendline for a calibration curve (AKA a standard curve) plotting absorbance (y-axis) against concentration (M, x-axis) is determined to be y = 4.586x + -0.0010 %3D The absorbance of a solution of unknown concentration is determined to be 0.68. Calculate the concentration of the unknown solution in M. Give your answer to thrėe decimal places.A 5.00×10−4 M solution of analyte is placed in a sample cell that has a pathlength of 1.00 cm. At a wavelength of 490 nm, the solution’s absorbance is 0.338. What is the analyte’s molar absorptivity at this wavelength?The standard curve was made by spectrophotographic analysis of equilibrated iron(III) thiocyanate solutions of known concentration. You are asked to analyze a Fe(SCN)2+ solution with an unknown concentration and an absorbance value of 0.392. The slope-intercept form of the equation of the line is y = 4538.1x +0.0077. The unknown was analyzed on the same instrument as the standard curve solutions at the same temperature. What is the Fe³+ concentration of the unknown solution? [Fe³+] = mol/L Absorbance Iron(III) thiocynate standard curve 1.0 V 0.5 0.0001 Fe³+ concentration (M) 0 0.0002
- if its absorbance is 0.900, find the molar absorptivity of a solution containing 3.0 x 10-3 g/L solute (MW=180) in a 4.0 cm cellThe molar absorptivity constant of a particular chemical is 2.31 M/cm. Determine the concentration of a solution made from this chemical that has an absorbance of 0.408 with a cell path length of 1.12 cm.Suppose that a solution has an absorbance of 0.250 at a wavelength of 450 nm. If the concentration of the solution is 22 μM, what is the value of the molar absorptivity? The data were taken with a standard 1-cm cuvette. molar absorptivity in (L cm^−1 mol^-1):
- Fe+3 (aq) + SCN – (aq) FeSCN +2 (aq) She mixes 4.00 mL of 2.00 mM SCN– and 5.00 mL of 2.00 mM Fe+3 ions, then diluting with 1.00mL of water to give a total volume of 10.00mL. She measures the absorbance of the solution asbeing 0.210. If she has previously calculated the molar absorbtivity constant (ε) of the product tobe 2583 cm–1 M–1, what is her best estimate for the K value for this reaction?The glucose content of samples can be determined using Nelson’s test. The equation of the line for the standard curve prepared for varying concentrations of glucose is y = 3.0x + 0.2. Based on this information, determine the glucose concentration (in M) of a mango preserve having an absorbance reading of 0.891.Calculate the molar absorptivity of a solute when its measured absorbance is 1.050 with a concentration of 1.45 x 10-3 M. Assume the path length of the cell is 1.0 cm.