A mixture is prepared by combining 11.34 mL of 2.36 x 103 M Fe(NO3)3 with 10.00 mL of 1.66 x 10-3 M KSCN. The solution turns red due to the formation of FeSCN2+. The absorbance is measured and, using a calibration plot, the [FESCN2*] at equilibrium is found to be 2.20 x 10-4 M. Complete the following ICE table Fe3+ SCN 1t FESCN2+ initial (M) (A) (B) (C)0 change (M) (D) (E) (F) equilibrium (M) (G) (H) (1) What is the value of K?
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- 10) Ce³+ exhibits pH dependent solubility. If Ce(NO3)3 is dissolved in an acidic solution to a concentration of 0.025 M, at what pH has 95% of the cerium been removed as the insoluble hydroxide salt? Ce(OH)3 pKsp=21.22+ For the aqueous [Ni(NH3) [Ni(NH3)]²+ complex K₁ = 5.50 × 108 at 25 °C. Suppose equal volumes of 0.0078M Ni(NO3), solution and 0.96M NH3 solution are mixed. Calculate the equilibrium molarity of aqueous Ni²+ ion. Round your answer to 2 significant digits. M 0x₁ x10 X ? ŚWhat mass of solid Lanthanum (III) oxalate nonahydrate { La2 ( C2O4 )3 ∙ 9 H2O } can be obtained from 650 mL of 0.0170 M aqueous solution of LaCl3 by adding a stoichiometric amount of sodium oxalate ? with solution/explanation
- Lanthanum and other rare-earth compounds are used in carbon arc lighting, specifically in the film and television industry for studio lighting and projection. A student in CHEM 2102 was traying to precipitate La3+ as La(OH)3 starting from acidic solution of 0.010 M La3+. (Ksp value for La(OH)3 =2 x10-21) Suggest a chemical reagent that can be used to precipitate La3+as La(OH)3 At what pH the precipitation will occur1. Calculate the solubility of solid Ca3(PO4)2(Ksp=1.3x10−32) in a 0.20 M Na3PO4 solution.If 150 mL 0.0180 M Ni(NO3)2 and 125 mL of 0.25 M ammonia (NH3) are diluted to 500 mL with deionized water. What is the concentration of Ni(NH3)42+ in solution assumed to be at equilibrium? Kr for [Ni(NH3)4²+] is 3.7 x 1016 O 724 x 102 M O 6.9 x 10¹ M O 0.018 M O 5.4 x 10-3 M
- 2. An iron ore was analyzed by dissolving a 1.1324 g sample in concentrated HC. The resulting solution was diluted with water, and the iron(III) was precipitated as hydrous oxide Fe,03 .XH20 by the addition of NH3. After filtration and washing, the residue was ignited at a high temperature to give 0.5394 g of pure Fe,03 (FW = 159.69). Calculate (a) the percent Fe (FW = 55.847) and (b) the percent Fe;04 (FW = 231.54) in the sample.A solution containing copper(II) nitrate (aq) first has some aqueous ammonia added to it. A white precipitate forms. Addition of more aqueous ammonia results in the precipitate dissolving, forming a clear dark blue solution. Write reactions for each step in the process. Hints: Ksp Cu(OH)2 = 2.2 X 10-20; Kb NH3 = 1.8 X 10-5 and Kf Cu(NH3)42+ = 1.1 X 1013Given that the Ksp for silver chloride is 1.76 x 10-10, and the Kf of silver(I) diammine cation [Ag(NH3)2 +] is 1.7 x 107, calculate the maximum number of grams of silver chloride that will dissolve in 250.0 mL of a 3.25 M solution of ammonia.
- For the aqueous [Hg14] complex K₁=6.76 × 10²⁹ at 25 °C. 2+ Suppose equal volumes of 0.0066M Hg(NO3), solution and 0.78M KI solution are mixed. Calculate the equilibrium molarity of aqueous Hg²+ ion. Round your answer to 2 significant digits. M x10 X ? ŚKs for Ca(OH)2(6) is 10-5.19. Please write out the reaction and K for the dissolution of this solid. Now write the equilibrium expression for this solid. What is the IAP? If [Ca2+1 = 10-2 M and pH is 8, will this solid form? Is there a range in pH where this will form?Consider the insoluble compound cobalt(II) carbonate, COCO3 . The cobalt(II) ion also forms a complex with ammonia. Write a balanced net ionic equation to show why the solubility of COCO3 (s) increases in the presence of ammonia and calculate the equilibrium constant for this reaction. 2+ For Co(NH3) 6² Kf = 7.7×104. Be sure to specify states such as (aq) or (s). I K= + +