6. What is the appropriate IUPAC name for compound shown?CH3lominoq-b-lylea) (1R,3S,5S)-1-bromo-3-tert-butyl-5-methylcyclohexaneb) (1R,3S,5R)-1-bromo-3-tert-butyl-5-methylcyclohexanec) (1R,3R,5S)-1-bromo-3-tert-butyl-5-methylcyclohexaned) (1S,3S,5S)-1-bromo-3-tert-butyl-5-methylcyclohexanee) None of above7. Which of the choices is an enantiomer of the compound shown?Brно-a)a) 1HOb) 2a)BrOH''OHb)OHHOBrHOc) 3b)HOH₂COH"OHOHOH8. What is the relationship between the two structures shown?HO-HOBr-HollandHOHHOCH3CH3OHHOa) same compoundb) enantiomersd) none of thesec) diastereomersouts ow9. Which choice correctly represents the structure below as a wedge-dash structure with any/all stereocenterscorrectly labeled with their absolute configuration?BrCICICI10. How many diastereomers are there for the compound shown?ONHCIOHOHPREISTE (dSd) 4Page 2 of 5OHOHOHd)OHHO*HO"OHOH720Br....Se) 5d)CIOHSon 240 3$100marmoal nouudilerpoRBrif) none of abovee)CIOHS 1. How many stereoisomers are there for the compound below?b) 2a) 1c) 42. What is the appropriate IUPAC name for compound shown?OHLa) Enantiomersd) constitution isomersa) (R)-4-methyl-2-pentanold) (S)-2-methyl-4-pentanol3. What is the relationship between the two structures below?a) Enantiomersd) constitution isomersb) diastereoisomerse) same compounds||||dd) 6BrBr4. What is the relationship between the two structures below?HO-H-OH-ОН.b) (S)-4-methyl-2-pentanole) none of aboveb) diastereoisomerse) same compoundsOHOHH-OHOHbHOe) 8Page 1 of 5OHf) none of above(c) (R)-2-methyl-4-pentanolc) different compoundsf) none of abovec) different compoundsf) none of aboveH OHHOH HO OH5. Which one of the following is the constitutional isomer of (2R,3R)-2,3-dibromopentane?a) (2S,3S)-2,3-dibromopentane(c) (2R,4S)-2,4-dibromopentaneb) (2S,3R)-2,3-dibromopentane(d) (2R,3R)-2,4-dibromopentane16

nomenclature rules for the cycloalkane: Identify the longest continuous carbon ring.Identify the…

6. What is the appropriate IUPAC name for compound shown? CH₂ Br H₂C CH3 CH3 a) (1R,3S,5S)-1-bromo-3-tert-butyl-5-methylcyclohexane b) (1R,3S,5R)-1-bromo-3-tert-butyl-5-methylcyclohexane c) (1R,3R,5S)-1-bromo-3-tert-butyl-5-methylcyclohexane d) (1S,3S,5S)-1-bromo-3-tert-butyl-5-methylcyclohexane e) None of above

6. What is the appropriate IUPAC name for compound shown? CH₂ Br H₂C CH3 CH3 a) (1R,3S,5S)-1-bromo-3-tert-butyl-5-methylcyclohexane b) (1R,3S,5R)-1-bromo-3-tert-butyl-5-methylcyclohexane c) (1R,3R,5S)-1-bromo-3-tert-butyl-5-methylcyclohexane d) (1S,3S,5S)-1-bromo-3-tert-butyl-5-methylcyclohexane e) None of above

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter23: Amines

Section: Chapter Questions

Problem 23.22P

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What is true about the relationship between the following compounds? CH3 CH3 CH; CH; CH3 CH3 A В O All three are stereoisomers of each other. OA and B are the same compound while C is a stereoisomer. All three are the same compound. A and B are the same while C is a conformer, all of the same compound . O A and C are the same while B is a stereoisomer.
A1. Draw the most stable conformations for: a)1-methyl-1-propylcyclohexane b)Trans-1-methyl-2-propylcyclohexane c)Cis-1-methyl-2-propylcyclohexane
Which compound has a higher boiling point: CH.CH.CH,NH, or CH:(CH),NH2 A) CH.CH.CH,NH, B) CH (CH.) NH, C) Not enough information is given to determine the boiling point D) They are stereoisomers and have identical boiling points
Compound 1 Br Bri НІ T ... H The correct IUPAC names are: Compound 2 H Br Br I.. H Br The compounds are diastereomers not isomeric enantiomers identical constitutional isomers Compound 1: (2R, 3R)-1,2,3-tribromobutane, Compound 2: (2S, 3R)-1,2,3-tribromobutane Compound 1: (2R, 3S)-1,2,3-tribromobutane, O Compound 1: (2R,3R)-1,2,3-tribromobutane, Compound 2: (2S,3S)-1,2,3-tribromobutane Compound 2: (2R, 3R)-1,2,3-tribromobutane O Compound 1: (2S,3S)-1,2,3-tribromobutane, Compound 2: (2R,3S)-1,2,3-tribromobutane
3. Draw the most stable chair conformation of (trans) 3-t-butylcyclohexanol. 4. State whether these two are: a) the same molecule b) different compounds that are not isomers c) constitutional isomers d) diastereomers e) enantiomers H CH3 CH₁ Br Br Br CH3 H Br H CH3
1. Name compounds by IUPAC nomenclature CH₂CH-COOH a ОН 2) Find all of the heterofunctional compounds among following: ОН 2 сн, -ен, -с NH, OH COOH CH-OH CH,COOH e b COOH H-C-OH н-с- -ОН COOH -СООН f с H₂C-C-CH₂ 0 COOH HO-C-CH,COOH CH,COOH CH2-CH-CH2; OH ОН ОН g d ОН HOOC–C–CH,COOH ОН HOỌC –COOH б ONa
Considering structures below, which of the following statements is true? O I H-C-O-CH₂ CH₂OH O || II HOCH₂CH₂-C-OH III HOCH₂CH₂-O-C-H A) I and II have different molecular formulas. B) I and III are structural isomers of each other. C) II and III are stereoisomers of each other. D) II and III are different conformations of the same compound. E) I and III are the same compound.
Draw the most stable conformations of the following compounds: a) trans-1,2-cyclohexanediol b) cis-1-t-butyl-2-methylcyclohexane c) trans-1-chloro-4-methylcyclohexane
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