4. Reactivity considerations suggest that an unknown compound, which has the mass spectrum shown in Fig. 2, is a vinyl halide. Combustion analysis gave the following results: Carbon, 35.06 %; Hydrogen, 6.62 %. In order to finish the combustion analysis properly, the operator needs to know which halide to test for. Which halide would you suggest? Postulate a molecular formula for this unknown compound. Explanation of the fragmentation pattern is not required! 100 80 60 40 20 % of base peak 41 40 80 Fig.2 M 121/123 136/138 120 160 m/e

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter14: Mass Spectrometry
Section: Chapter Questions
Problem 14.27P: Following is the mass spectrum of an unknown compound. The two highest peaks are at m/z 120 and 122....
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4. Reactivity considerations suggest that an unknown compound, which has the mass spectrum shown in Fig. 2, is a vinyl
halide. Combustion analysis gave the following results: Carbon, 35.06 %; Hydrogen, 6.62 %. In order to finish the
combustion analysis properly, the operator needs to know which halide to test for. Which halide would you suggest?
Postulate a molecular formula for this unknown compound. Explanation of the fragmentation pattern is not required!
100
80
40
20
% of base peak
29
41
40
57
80
Fig.2
М'
121/123 136/138
120 160
m/e
Transcribed Image Text:4. Reactivity considerations suggest that an unknown compound, which has the mass spectrum shown in Fig. 2, is a vinyl halide. Combustion analysis gave the following results: Carbon, 35.06 %; Hydrogen, 6.62 %. In order to finish the combustion analysis properly, the operator needs to know which halide to test for. Which halide would you suggest? Postulate a molecular formula for this unknown compound. Explanation of the fragmentation pattern is not required! 100 80 40 20 % of base peak 29 41 40 57 80 Fig.2 М' 121/123 136/138 120 160 m/e
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