1. The mass spectrum of 3-hexanol is given below. 100 Intensity 55 80- 60- 40 40 20 20 59 73 3-Hexanol El MW = 102 OH 0 0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 m/z (a) Rationalize the small size of the molecular ion peak at m/z 102. (b) Assign structures to all the labeled species and rationalize their formation.
1. The mass spectrum of 3-hexanol is given below. 100 Intensity 55 80- 60- 40 40 20 20 59 73 3-Hexanol El MW = 102 OH 0 0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 m/z (a) Rationalize the small size of the molecular ion peak at m/z 102. (b) Assign structures to all the labeled species and rationalize their formation.
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter14: Mass Spectrometry
Section: Chapter Questions
Problem 14.24P
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