In the Caprolactam production process, distillation is used for the separation of cyclohexane and cyclohexanol. The feed to the column is 400 ktons per year (1yr = 8000hr) and it contains z=58 mol% cyclohexane. The specifications for the top and bottom product are respectively xp-98 mol% and XB-2 mol% cyclohexane. The column is operated at atmospheric pressure. The vapor-to-feed ratio in the feed is 10 mol %. The xy-diagram for the system can be found on the next slide.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
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d) Graphically determine the minimum reflux ratio

18
19
Tutorial 3 - Question Q3 Solution
d) Graphically determine the minimum reflux ratio and compare to the shortcut model
prediction.
1
0.9
0.8
0.7
0.6
y 0.5
0.4
0.3
0.2
0.1
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X
0.9
0.8
0.7
0.6
y 0.5
0.4
0.3
0.2
0.1
Pinch point
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
X
The vapour-to-feed ratio is given:
VE
F
= 0.1
The quality of the feed:
VE
LE F-V²=1-/=0
q= =
F
The q-line:
y = -
Tutorial 3 - Question Q3 Solution
d) Graphically determine the minimum reflux ratio and compare to the shortcut model
prediction.
1
9
q
·x +
y = -9x + 5.8
1
1-q
University of
Strathclyde
Engineering
Points (0.58,0.58) and (0.54,0.94)
are on the q-line
Operating line:
R
y =
R + 1
Z
The pinch point is: (0.56,0.75)
Therefore, two points on the
operating line are:
(xD, XD) and (0.56,0.75)
x +
In these conditions:
Rmin
Rmin +1
Rmin = 1.22
So, the slope of the operating line is:
XD - 0.75
XD - 0.56
= 0.55
University of
Strathclyde
Engineering
= 0.55
0.9
1
R + 1
-XD
Transcribed Image Text:18 19 Tutorial 3 - Question Q3 Solution d) Graphically determine the minimum reflux ratio and compare to the shortcut model prediction. 1 0.9 0.8 0.7 0.6 y 0.5 0.4 0.3 0.2 0.1 0 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 X 0.9 0.8 0.7 0.6 y 0.5 0.4 0.3 0.2 0.1 Pinch point 0 0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1 X The vapour-to-feed ratio is given: VE F = 0.1 The quality of the feed: VE LE F-V²=1-/=0 q= = F The q-line: y = - Tutorial 3 - Question Q3 Solution d) Graphically determine the minimum reflux ratio and compare to the shortcut model prediction. 1 9 q ·x + y = -9x + 5.8 1 1-q University of Strathclyde Engineering Points (0.58,0.58) and (0.54,0.94) are on the q-line Operating line: R y = R + 1 Z The pinch point is: (0.56,0.75) Therefore, two points on the operating line are: (xD, XD) and (0.56,0.75) x + In these conditions: Rmin Rmin +1 Rmin = 1.22 So, the slope of the operating line is: XD - 0.75 XD - 0.56 = 0.55 University of Strathclyde Engineering = 0.55 0.9 1 R + 1 -XD
In the Caprolactam production process, distillation is used for
the separation of cyclohexane and cyclohexanol. The feed to
the column is 400 ktons per year (1yr = 8000hr) and it contains
z=58 mol% cyclohexane. The specifications for the top and
bottom product are respectively xD=98 mol% and X²=2 mol%
cyclohexane. The column is operated at atmospheric pressure.
The vapor-to-feed ratio in the feed is 10 mol%. The xy-diagram
for the system can be found on the next slide.
Transcribed Image Text:In the Caprolactam production process, distillation is used for the separation of cyclohexane and cyclohexanol. The feed to the column is 400 ktons per year (1yr = 8000hr) and it contains z=58 mol% cyclohexane. The specifications for the top and bottom product are respectively xD=98 mol% and X²=2 mol% cyclohexane. The column is operated at atmospheric pressure. The vapor-to-feed ratio in the feed is 10 mol%. The xy-diagram for the system can be found on the next slide.
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