14 From the following spectral data, and using Tanabe- Sugano diagrams (Figure 11.7), calculate A for the following: 0 a. [Cr(C2O4)3]³, which has absorption bands at 23,600 and 17,400 cm 1. A third band occurs well into the ultraviolet. - b. [Ti(NCS)6]³, which has an asymmetric, slightly split band at 18,400 cm 1. (Also, suggest a reason for the splitting of this band.) c. [Ni(en)3]2+, which has three absorption bands: 11,200, 18,350, and 29,000 cm d. [VF]³, which has absorption bands at 14,800 and 23,250 cm ¹, plus a third band in the ultraviolet. Also calculate B for this ion. e. The complex VC13(CH3CN)3, which has absorption bands at 694 and 467 nm. Calculate A. and B for this complex.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes
Section: Chapter Questions
Problem 33P
Question
14 From the following spectral data, and using Tanabe-
Sugano diagrams (Figure 11.7), calculate A for the
following:
0
a. [Cr(C2O4)3]³, which has absorption bands at 23,600
and 17,400 cm 1. A third band occurs well into the
ultraviolet.
-
b. [Ti(NCS)6]³, which has an asymmetric, slightly
split band at 18,400 cm 1. (Also, suggest a reason
for the splitting of this band.)
c. [Ni(en)3]2+, which has three absorption bands:
11,200, 18,350, and 29,000 cm
d. [VF]³, which has absorption bands at 14,800 and
23,250 cm ¹, plus a third band in the ultraviolet.
Also calculate B for this ion.
e. The complex VC13(CH3CN)3, which has absorption
bands at 694 and 467 nm. Calculate A. and B for
this complex.
Transcribed Image Text:14 From the following spectral data, and using Tanabe- Sugano diagrams (Figure 11.7), calculate A for the following: 0 a. [Cr(C2O4)3]³, which has absorption bands at 23,600 and 17,400 cm 1. A third band occurs well into the ultraviolet. - b. [Ti(NCS)6]³, which has an asymmetric, slightly split band at 18,400 cm 1. (Also, suggest a reason for the splitting of this band.) c. [Ni(en)3]2+, which has three absorption bands: 11,200, 18,350, and 29,000 cm d. [VF]³, which has absorption bands at 14,800 and 23,250 cm ¹, plus a third band in the ultraviolet. Also calculate B for this ion. e. The complex VC13(CH3CN)3, which has absorption bands at 694 and 467 nm. Calculate A. and B for this complex.
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