Quiz 5 KEY
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1B
Subject
Chemistry
Date
Jan 9, 2024
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Chem1B-02 Quiz #5
Lizeth Hernandez Martinez
TOTAL POINTS
10 / 20
QUESTION 1
1
Colored TM complexes
2 / 5
- 0 pts
Correct
✓
- 2 pts
Color comes from electronic transitions
between d orbitals
✓
- 0 pts
Did not mention Sc3+/Zn2+
- 3 pts
Incorrect
✓
- 1 pts
Partially incorrect
- 5 pts
No answer
- 0 pts
Zn2+ has d electrons
QUESTION 2
Co2+
15 pts
2.1
Electron configuration
3 / 3
✓
- 0 pts
Correct
- 2 pts
TMs lose 4s electrons before 3d electrons
- 2 pts
Incorrect electron configuration
- 1 pts
Missing n = 3
2.2
Octahedral energy diagram
3 / 6
- 0 pts
Correct
- 2 pts
Missing labeling of d orbitals
- 0 pts
Incorrect # electrons
- 2 pts
Incorrect d splitting
- 0.5 pts
Paired electrons should be opposite spins
✓
- 1 pts
Relative energy spacing
✓
- 1 pts
Electrons are not in low spin configuration
✓
- 1 pts
Partially incorrect d orbital labels
- 2 pts
Incorrect labeling of d orbitals
- 1 pts
Incorrect # of electrons
- 6 pts
No answer
2.3
Tetrahedral energy diagram
2 / 6
- 0 pts
Correct
✓
- 2 pts
Incorrect splitting of d orbitals
- 2 pts
Missing d orbital labels
✓
- 1 pts
Should be high spin configuration
- 0.5 pts
Paired electrons should be opposite spins
- 0 pts
Incorrect # of electrons
- 1 pts
Relative energy spacing
- 2 pts
Fill lower energy orbitals before higher
energy
✓
- 1 pts
Partially incorrect d orbital labels
- 1 pts
Incorrect # of electrons
- 2 pts
Incorrect d orbital labels
- 1 pts
Incorrect filling of electrons
Page 1
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Related Questions
354
Example:
Calculate the spin-only magnetic moment for the following atoms and ions.
(Remember the rules for electron configurations associated with the ionization of
transition metals
Fe
Fe2+
Cr
Cr3+
Cu
Cu2+
-1
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Which absorbance spectrum from the previous problem represents the dye solution with the greatest
concentration?
1.4
1.2
Curve 3
0.8
0.6
Curve 2
Curve 1
0.4
0.2
0.2
Wavelength (nm)
O All three are approximately the same concentration
O Curve 3
O Cannot be determined from the information given
Curve 2
Curve 1
700
580
Absorbance
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a) Hg2Cl2 1. Green
b) PbCrO4 2. Black
c) NiS 3. Yellow
d) (NiCl4)2- 4. Brown
e) Fe(OH)3 5. White
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Calculate the p-function for each ion.
[Rb*] = 0.395 M
pRb =
[Co?+] = 6.65 x 10-6 M
pCo =
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2
5
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3
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F1
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F2
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Based on the following spectrum, what color would you expect this solution to
appear?
WE
1.8
1.6
Absorbance
1.4
1.2
1
0.8
0.6
0.4
0.2
0
380
Trouble viewing?
Oa) red
Ob) yellow
80
F3
O d) purple
c) orange
e) blue
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430
Q
F4
%
сч оро
5
480
0
F5
R T
A
6
530
580
Wavelength (nm)
F6
Y
&
7
K
F7
630 nm-
Orange
590 nm
630
U
*
Red
Yellow
8
F8
750 nm 400 nm
680
560 nm
I
(
9
F9
S D F G H J K
Violet
Green
)
0
430 nm
480 nm
Blue
F10
0
L
P
F11
Ć
+
{
[
arrow_forward
Which ion will be attracted to a magnetic field?
A) C²⁺
B) O²⁻
C) F⁺
D) Be
E) All of the above
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QUESTION 6
In a polarised electronic absorption spectrum for a molecule with D3h point symmetry a a2" to e' transition is allowed in which linear polarisation?
X
y
Not linearly polarised
Z
arrow_forward
You have the following solutions, A-E. Which solution has the highest absorbance value at 280 nm?
Solution A: 1.0 mM Gly-Ser
Solution B: 10 mM Gly-Ser
Solution C: 1.0 mM Phe-Ser
Solution D: 1.0 mM Tyr-Ser
Solution E: 1.0 mM Trp-Ser
Solution C
Solution E
Solution B
Solution D
Solution A
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I wanna know how to make V = abc(1 − cos2α − cos2β − cos2γ + 2 cos α cos β cos γ)1/2 (the volume of triclinic). When a≠b≠c, α≠β≠γ ≠90°
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Which of the following statements regarding IR spectroscopy is incorrect?
arrow_forward
V
67°F
cloud,
energy
Which is the ground state?
Use this diagram to complete the table below.
25
C
Explanation
E
How many excited states are there?
Check
How many lines are in the absorption line spectrum?
(pick one) ✓
0
0
1 Search LACROECO CON
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1. Which proton has the largest multiplicity? Smallest multiplicity?
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9. Which of the following is paramagnetic?
Z of Zn = 30, Cr = 24, O =8
Group of answer choices
a) Zn+2
b) Cr+2
c) Zn
d) O-2
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This arrangement of water molecules in the pore of aquaporins
Omo=c
-O=o=c
00101c
H-N Asn
H-N Asn
-O=³0=c
-O=o=c
-Omo=c
allows hydrated ions to flow through the pore
prevents movement of protons through the pore
O facilitates proton hopping from water molecule to water molecule in the
pore
O both A and C
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I have 4 Questuion
Q1: find the A , T , T% of a 2.4X10-3 mol L-1 solution of a substance whose molar absorptivity is 313 L M-1 cm -1 at 520 nm when measured in a cell of 2.00 cm pathlength ؟
Q2: A sample in a 1 cm cuvette transmits 79% of light at 280 nm , what is the absorbance ? if the molar extinction coefficient is 2.0 M-1 cm-1 , what is the concentration of the sample ?
Q3 : the aspirin an analgesic form complex with metal ion which has a molar absorpitvity of 8000 L M-1 cm-1 at ( lenada max 435 nm ) . calculate the absorbance of 6.77 X 10-5 M solution of the complex measured in a 1.00 cm cell at 435 nm ?
Q4 :Find the A and T% of a 6.5X10-4 Mol L-1 solution of a drug ( molecular weigth 200 ) whose absorpitvity is 0.026 L cm-1 g-1 at 520 nm when measured in a cell of 2.00 cm pathlength ?
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Name:
Intensity
80
1s
70
Peak X
8
7
Due: Wed., 3/1/23
Peak Y
Page 2 / 9
40
Binding Energy (MJ/mol)
D
t
8
I
2
2. A sample containing atoms of C and F was analyzed using x-ray photoelectron spectroscopy.
The portion of the spectrum showing the Is peaks for atoms of the two elements is shown above.
Which of the following correctly identifies the 1s peak for the F atoms and provides an
appropriate explanation?
(A) Peak X, because F has a smaller first ionization energ than C has.
(B) Peak X, because F has a greater nuclear charge than C has.
(C) Peak Y, because F is more electronegative that C is.
(D) Peak Y, because F has a smaller atomic radius that C has.
+
0
AP Chemistry
Sign out
arrow_forward
Unrounded
Rounded
ε∗,L/μmolε∗,L/μmol
0.0259825
0.0260
heres data:
TZ #
Concentration
Absorbance at 430 nmnm
1
33.6480
0.931
2
25.2360
0.757
3
16.8420
0.210
4
8.41200
0.137
5
4.20600
0.122
arrow_forward
t-Bu
Me
Pt
Ме
1
t-Bu
assign point group of this complex
arrow_forward
1 Draw both
a state
of
التاريخ
الموضوع :
an orbital Correler Thorant
Correlation diagran for [25+? reaction
the Sophies
+
a
0
Endo 99% Ex01
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A solution of copper(II) sulfate is observed to be blue in color. The maximum absorbance is expected to occur in what wavelength range?
500-560 nm (green)
380-435 nm (violet)
610-750 nm (red)
580-595 nm (yellow)
435-480 nm (blue)
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5) Given the absorbance spectrum shown below, what wavelength of light would you
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Absorbance
0.8
0.6
0.4
1
0.2
0
350
400
Absorbance vs. Wavelength for Nickel(II)
ion
450
500
550
600
650
Wavelength (nm)
700
750
800
850
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5.62 x10-7
ppm
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