Appl Of Ms Excel In Analytical Chemistry
2nd Edition
ISBN: 9781285686691
Author: Crouch
Publisher: Cengage
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Treatment of ammonia with phenol in the presence of hypochlorite yields indophenol, a blue product that absrobs light at
625 nm, which çan be used for the spectrophotometric determination of ammonia.
gan
OCF
OH + NH3
indophenol anion
To determinè the ammonia concentration in a sample of lake water, three samples are prepared. In sample A, 10.0 mL of lake
water is mixed with 5 mL of phenol solution and 2 mL of sodium hypochlorite solution, and diluted to 25.0 mL in a volumetric
flask. In sample B, 10.0 mL of lake water is mixed with 5 mL of phenol solution, 2 mL of sodium hypochlorite solution, and
2.50 mL of a 5.50 x 10-4 M ammonia solution, and diluted to 25.0 mL. Sample C is a reagent blank. It contains 10.0 mL of
distilled water, 5 mL of phenol solution, and 2 mL of sodium hypochlorite solution, diluted to 25.0 mL. The absorbance of the
three samples is then measured at 625 nm in a 1.00 cm cuvette. The results are shown in the table.
Sample Absorbance (625 nm)
A
0.361
B
0.608
C…
WARIARTAM
2. 1.2589 g of a certain brand of milk powder required 25.89 mL of 0.01873M EDTA to titrate the calcium
contained in the sample.
(a) What is the percent calcium in the sample?
(b) Would the true result be higher, lower, or not be affected if the milk powder sample has been slightly
wet?
4. The molar absorptivities of the indicator weak acid HIn (K₁ = 1.42 x 105) and its conjugate
base In at 570 were determined as ε(HIn) = 7120 and ɛ(In) = 961. The optical length b = 1.00
cm. (a) What is the absorbance of an unbuffered indicator solution having total indicator
concentration 8.0 × 10%.
(b) What is the absorbance of a buffered indicator solution having total indicator concentration
8.0 x 105 and pH = 6.5.
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