Appl Of Ms Excel In Analytical Chemistry
Appl Of Ms Excel In Analytical Chemistry
2nd Edition
ISBN: 9781285686691
Author: Crouch
Publisher: Cengage
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A titrimetric method for the determination of calcium in limestone was tested with the analysis of a NIST limestone containing 30.15% CaO. The mean of the four analyzes is 30.26% CaO with a standard deviation of 0.085%. From the data accumulated from many analyzes, s→ϭ=0.094% CaO was found.a) Do the data indicate the presence of systematic error at the 95% confidence level?b) When a value for ϭ is unknown, do the data show a systematic error at the 95% confidence level?
For the determination of iron in used jet engine oil, 30 analyzes with 3 repetitions each were made by atomic absorption method and the standard deviation was found s=2.4 µg Fe/mL. Since this standard deviation value is close to the ϭ value, the iron concentration of 18.5 µg Fe/mL(a) by a single analysis,(b) as the average of the two analyzes,(c) Calculate the 80% and 95% confidence intervals if found as the mean of four analyses.
In replicate analyses, the carbohydrate content of a glycoprotein (a protein with sugars attached to it) is found to be 12.6, 11.9, 13.0, 12.7, and 12.5 g of carbohydrate per 100 g of protein. (a) Find the mean of the measurements. (b) Find the standard deviation (s). (c) Find the 90% confidence intervals for the carbohydrate content. (d) If the mean and s are unchanged, but there are 10 measurements (N=10) instead of 5, what would be the confidence interval? (e) How does increasing the number of replicate measurements affect the reliability of measurements? Explain your answer. (Hint: better precision gives smaller confidence intervals)
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