Why cis-Ru(II)Cl2(DMSO)4 reacts with pyridine, et cetera, to give substitution of the DMSO but not the chloride ligands, but trans-Ru(II)Cl2(py)4 react with suitable Na+ and K+ salts in aqueous pyridine to afford chloride-substituted derivatives. write the reactions equations.

Why cis-Ru(II)Cl2(DMSO)4 reacts with pyridine, et cetera, to give substitution of the DMSO but not the chloride ligands, but trans-Ru(II)Cl2(py)4 react with suitable Na+ and K+ salts in aqueous pyridine to afford chloride-substituted derivatives. write the reactions equations.

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds

Section: Chapter Questions

Problem 105QRT

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Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.

Question

Why cis-Ru(II)Cl₂(DMSO)₄ reacts with pyridine, et cetera, to give substitution of the DMSO but not

the chloride ligands, but trans-Ru(II)Cl₂(py)₄ react with suitable Na+ and K+ salts in aqueous

pyridine to afford chloride-substituted derivatives. write the reactions equations.

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Step 1: Trans effect

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Step 2: Substitution of DMSO in cis-Ru(II)Cl2(DMSO)4

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Step 3: Substitution of Cl in trans-Ru(II)Cl2(py)4

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