Why are the observed configurations of, for example, trigonal bipyramidal structures  sometimes different for different measuring techniques?

Introductory Chemistry: A Foundation
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Author:Steven S. Zumdahl, Donald J. DeCoste
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Chapter12: Chemical Bonding
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Problem 27CR: What are the representative elements? In what region(s) of the periodic table are these elements...
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Why are the observed configurations of, for example, trigonal bipyramidal structures 
sometimes different for different measuring techniques? 

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