Answered: Which of the following reagents will…

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Which of the following reagents will oxidize secondary alcohols to ketones 1. CrO3, H2SO4 2. PCC 3. PCI 3 4. SOCI₂

Chemistry & Chemical Reactivity

9th Edition

ISBN:9781133949640

Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Chapter23: Carbon: Not Just Another Element

Section: Chapter Questions

Problem 45PS

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Concept explainers

Diol

In chemistry there are so many chemical compounds that have a hydroxyl group but a chemical compound having two hydroxyl groups (-OH) is termed as a diol. It also implies the presence of two alcohols whereas polyols contain two or more than two hydroxyl groups (-OH). Glycol or 1,2-diol is an aliphatic diol that has two alcohol groups on adjacent carbon atoms. In industries, the most commonly used diol is ethylene glycol.

Question

Which of the following reagents will oxidize secondary alcohols to ketones?
1. CrO3, H2SO4
2. PCC
3. PC13
4. SOCI₂
only 1
only 2
only 3
only 4
1 and 2

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