What reagents and experimental conditions will bring about each step in the conversion of toluene to 4-hydroxybenzoic acid? CH3 CH ÇOOH ÇOOH COOH (2) (3) (4) NO, NO, NH, OH
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- Nonconjugated , -unsaturated ketones, such as 3-cyclohexenone, are in an acid-catalyzed equilibrium with their conjugated , -unsaturated isomers. Propose a mechanism for this isomerization.When 2-pentene is treated with Cl2 in methanol, three products are formed. Account for the formation of each product (you need not explain their relative percentages).H3C N- H₂NNH₂ H⭑ CH3 H3C IN CH3 Hydrazine reacts with 2,4-pentanedione to yield 3,5-dimethylpyrazole. Including protonations and deprotonations, the reaction takes 12 steps. Write out the mechanism on a sheet of paper and then draw the structure of the product of step 6. • You do not have to consider stereochemistry. •You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading. • In an elimination step, include the structure of the leaving group, but draw it in its own sketcher. Separate structures with + signs from the drop-down menu. ? Sn th Previous Next
- What reaction conditions are needed to convert (R)-2-ethyl-2- methyloxirane to (R)-2-methylbutane-1,2-diol ?Acid-catalyzed dehydration of 3-methyl-2-pentanol gives three alkenes: 3-methyl-1-pentene, 3-methyl-2-pentene, and 3-methylenepentane. Draw the structure of the carbocation intermediate leading to the formation of 3-methyl-2-pentene.Write the appropriate reagents, conditions and products for the following electrophilic aromatic substitutions: COOH H₂ (3) Pt NO₂ ~
- Compound Y has molecular formula C,H12. Hydrogenation of compound Y produces methylcyclohexane. Treatment of compound Y with HBr in the presence of peroxides produces the following compound: Br Draw the product(s) when compound Y undergoes ozonolysis.What alkene is needed to synthesize each 1,2-diol using [1] OsO4 followed by NaHSO3 in H2O; or [2] CH3CO3H followed by −OH in H2O?The following are intermediate products in the stepwise synthesis of compound 1 from benzene. Give the correct sequence of reactions with the appropriate reagents that will lead to the correct intermediate products and final product. Br Br Br 1 2 4 3 5
- Questão 10A certain hydrocarbon had the molecular formula C16H26 and contained two triple bonds. Ozonolysis resulted in CH3(CH2)4CO2H and HO2CCH2CH2CO2H as the only products. What is the reasonable structure for this hydrocarbon? Hexadec-6,10-dino undec-1,5-dino Hept-1,5-dino hex-1,5-dino nahWhen the following compound is treated with a mixture of nitric and sulfuric acids, which of the following will be produced? O 5-chloro-2-nitrotoluene O 3-chloro-2-nitrotoluene O a mixture of 5-chloro-2-nitrotoluene. 3-chloro-4-nitrotoluene, 3-chloro-2-nitrotoluene, and 5-chloro-3-nitrotoluene O an equimolar mixture of 3-chloro-2-nitrotoluene. 5-chloro-2-nitrotoluene, and 3-chloro-4-nitrotoluene O 5-chloro-3-nitrotoluene O a mixture of 3-chloro-4-nitrotoluene (major) and 5-chloro-2-nitrotoluene (minor) O3-chloro-4-nitrotolueneDraw the structure of the starting material needed to make 2-methylhept-3-yne using sodium amide in liquid ammonia, followed by 1-bromopropane. The starting hydrocarbon must have no more than five carbons 1) NaNH2, NH3() NaBr + 2) CHзCH2CH2Br