What are the multiple steps after the hemiacetal, to get to the final product? hemiactal C CH₂OH H C -OCH 3 Final Product он > Multiple Steps Show all
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- illustrate how each reactant appeared prior to the reaction and how the product appeared after the reaction. 2Na+2H₂O --> 2NaOH+H₂Identify starting materials that would make the following acetal:Mustard gas, Cl¬CH2CH2¬S¬CH2CH2¬Cl, was used as a poisonous chemical agentin World War I. Mustard gas is much more toxic than a typical primary alkyl chloride. Itstoxicity stems from its ability to alkylate amino groups on important metabolic enzymes,rendering the enzymes inactive.(a) Propose a mechanism to explain why mustard gas is an exceptionally potent alkylatingagent
- What would be the major product if diethyl malonate (EtO2CCH2CO2Et) was decarboxylated using H3O+ and heat? A. CH3CH2CO2H B. CH3CO2H C. CH2(CO2H)2 D. CH3CO2EtShow how m-toluidine can be converted tom-toluidineCH3 NH2the following compounds, using any necessary reagents.m-toluonitrile(a) CH3 C N CH3 CH2NH2m-methylbenzylamine(b)m-iodotolueneRank the compounds in each set in order of increasing acid strength.(a) CH3CH2COOH CH3CHBrCOOH CH3CBr2COOH
- What is the major product obtained from the reaction of 2-ethyloxirane with each of the following reagents? a. 0.1 M HCl b. CH3OH>HCl c. 0.1 M NaOH d. CH3OH/CH3O-What products are obtained from the reaction of the following compound with H2CrO4 + Δ?The base-promoted rearrangement of an a-haloketone to a carboxylic acid, known as the Favorskii rearrangement, is illustrated by the conversion of 2-chlorocyclohexanone to cyclopentanecarboxylic acid. Jo Han Sow La NaOH, THF O Nat H3O+ OH NaOH, THF The mechanism involves the following 5 steps: -ō cyclopropanone intermediate 1. Abstraction of a proton to form enolate anion 1; 2. Formation of a cyclopropanone intermediate 2 with expulsion of chloride ion; 3. Addition of hydroxide ion to form tetrahedral intermediate 3; 4. Collapse of the tetrahedral intermediate and breakage of the three-membered ring to form carbanion intermediate 4; 5. Proton transfer to form the rearranged carboxylic acid. For the following reaction, draw the reaction out on paper, and then draw the structure of cyclopropanone intermediate 2 in the window. 1. NaOH, THF 2. H3O* OH
- Choose the best reagents to complete the following reaction. Option E is (CH2OH)2, TSOH (Please show reaekson and don't use hend raiting please)Show how m-toluidine can be converted tom-toluidineCH3 NH2the following compounds, using any necessary reagents.m-toluonitrile(a) CH3 C N CH3 CH2NH2m-methylbenzylamine(b)m-iodotolueneCH I 3 (c)m-cresol(d) CH3 OH3-methyl-4-nitroanilineCH3 NH2O2N(e)NHCH3N-cyclopentyl-m-toluidineShow how each transformation may be accomplished by using a nitrile as an intermediate. You may use any necessary reagents.(a) hexan@1@ol S heptan@1@amine(b) cyclohexanecarboxamide S cyclohexyl ethyl ketone(c) octan@1@ol S decan@2@one