Use the graph below to answer the following questions. Provide a short reasoning for your answers. 13 11 9 pH 7 5 3 1 5 10 15 20 Volume added (mL) Find the Ko of the base used. ( In what region is there more base than conjugate acid ion? (1 Determine the concentration of acid used if this represents the titration of 30 ml of 0.25 M base. ( Given the in. ation in the table below, suggest a suitable indicator for this titration. 11 marll 25

Use the graph below to answer the following questions. Provide a short reasoning for your answers. 13 11 9 pH 7 5 3 1 5 10 15 20 Volume added (mL) Find the Ko of the base used. ( In what region is there more base than conjugate acid ion? (1 Determine the concentration of acid used if this represents the titration of 30 ml of 0.25 M base. ( Given the in. ation in the table below, suggest a suitable indicator for this titration. 11 marll 25

Chemistry

9th Edition

ISBN:9781133611097

Author:Steven S. Zumdahl

Publisher:Steven S. Zumdahl

Chapter15: Acid-base Equilibria

Section: Chapter Questions

Problem 9RQ: What is an acidbase indicator? Define the equivalence (stoichiometric) point and the end point of a...

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In an acid-base titration, 21.16 mL of an NaOH solution are needed to neutralize 20.04 mL of a 0.0997 M HCl solution. To find the molarity of the NaOH solution, we can use the following procedure: First note the value of MH in the HCl solution. ____________M Find MOH- in the NaOH solution. Use Eq.3. ____________M Obtain MNaOH from MOH. ____________M
Enough water is added to the buffer in Question 30 to make the total volume 5.00 L. (a) Calculate the pH of the buffer. (b) Calculate the pH of the buffer after adding 0.0250 mol of HCl to 0.376 L of the buffer. (c) Calculate the pH of the buffer after adding 0.0250 mol of KOH to 0.376 L of the buffer. (d) Compare your answers to Question 30 (a-c) with your answers to (a-c) of this problem. (e) Comment on the effect of dilution on the pH of a buffer and on its buffer capacity. Â
Each symbol in the box below represents a mole of a component in one liter of a buffer solution; represents the anion (X-), = the weak acid (HX), = H+, and =OH. Water molecules and the few H+ and OH- ions from the dissociation of HX and X- are not shown. The box contains 10 mol of a weak acid, , in a liter of solution. Show what happens upon (a) the addition of 2 mol of OH- (2 ). (b) the addition of 5 mol of OH- (5 ). (c) the addition of 10 mol of OH- (10 ). (d) the addition of 12 mol of OH- (12 ). Which addition (a)-(d) represents neutralization halfway to the equivalence point?
Methyl orange, HMO, is a common acid-base indicator. In solution it ionizes according to the equation: HMOaqH+aq+MO-aqredyellow If methyl orange is added to distilled water, the solution turns yellow. If 1 drop or two of 6 M HCl is added to the yellow solution, it turns red. If to that solution one adds a few drops of 6 M NaOH, the color reverts to yellow. a. Why does adding 6 M HCl to the yellow solution of methyl orange tend to cause the color to change to red? Note that in solution HCl exists as H+ and Cl- ions. b. Why does adding 6 M NaOH to the red solution tend to make it turn back to yellow? Note that in solution NaOH exists as Na+ and OH- ions. How does increasing OH- shift Reaction 3 in the discussion section? How would the resulting change in H+ affect the dissociation reaction of HMO?
A solution has a pH of 4.5. What would be the color of the solution if each of the following indicators were added? (See Fig. 14-8.) a. methyl orange b. alizarin c. bromcresol green d. phenolphthalein
What is an acidbase indicator? Define the equivalence (stoichiometric) point and the end point of a titration. Why should you choose an indicator so that the two points coincide? Do the pH values of the two points have to be within 0.01 pH unit of each other? Explain.
Consider the titration of HF (K a=6.7104) with NaOH. What is the pH when a third of the acid has been neutralized?
Consider a solution formed by mixing 100.0 mL of 0.10 M HA (Ka = 1.0 106), 100.00 mL of 0.10 M NaA. and 100.0 mL of 0.10 M HCl. In calculating the pH for the final solution, you would make some assumptions about the order in which various reactions occur to simplify the calculations. State these assumptions. Does it matter whether the reactions actually occur in the assumed order? Explain.