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There are two isomerism in coordination complexes which are structural isomerism and stereoisomerism. (a). Sketch the possible structures for the complexes below. (i). [Co(NH3)sBr][SO4] (ii). [CCCI(OH2)s]Cl2.H20 (b) Identify the type of isomerism for the compounds in (a). (c) Predict the chemical tests you would use to distinguish between the isomers in (a).

There are two isomerism in coordination complexes which are structural isomerism and stereoisomerism. (a). Sketch the possible structures for the complexes below. (i). [Co(NH3)sBr][SO4] (ii). [CCCI(OH2)s]Cl2.H20 (b) Identify the type of isomerism for the compounds in (a). (c) Predict the chemical tests you would use to distinguish between the isomers in (a).

Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter22: The Chemistry Of The Transistion Elements
Section22.4: Structures Of Coordination Compounds
Problem 4RC
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Kindly answer question a, b, c

There are two isomerism in coordination complexes which are structural isomerism and stereoisomerism. (а). Sketch the possible structures for the complexes below. (i). [Co(NH3)sBr][SO4] (ii). [CCCI(OH2)s]Cl2.H20 (b) Identify the type of isomerism for the compounds in (a). (c) Predict the chemical tests you would use to distinguish between the isomers in (a). (d). When the bidentate neutral ethylenediamine (en, -NH2CH2CH2NH2-) reacts with Co(III) chloride, Co(II) isomers of [Co(en),] are formed. (1). Illustrate the 3-dimensional structures of the isomers. (ii). Identify the type of isomerism.
Transcribed Image Text:There are two isomerism in coordination complexes which are structural isomerism and stereoisomerism. (а). Sketch the possible structures for the complexes below. (i). [Co(NH3)sBr][SO4] (ii). [CCCI(OH2)s]Cl2.H20 (b) Identify the type of isomerism for the compounds in (a). (c) Predict the chemical tests you would use to distinguish between the isomers in (a). (d). When the bidentate neutral ethylenediamine (en, -NH2CH2CH2NH2-) reacts with Co(III) chloride, Co(II) isomers of [Co(en),] are formed. (1). Illustrate the 3-dimensional structures of the isomers. (ii). Identify the type of isomerism.
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