The treatment of chlorobenzene with potassium amide in liquid ammonia results in the formation of aniline. Propose four experiments to distinguish between the two mechanisms given below CI NH2 NH2 CI- NH2 NH2 + NH3

The treatment of chlorobenzene with potassium amide in liquid ammonia results in the formation of aniline. Propose four experiments to distinguish between the two mechanisms given below CI NH2 NH2 CI- NH2 NH2 + NH3

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter18: Ethers And Epoxides; Thiols And Sulfides

Section18.SE: Something Extra

Problem 33MP: When 2-methyl-2, 5-pentanediol is treated with sulfuric acid, dehydration occurs and 2,...

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Concept explainers

Organometallic compounds of d-block elements

The transition metals can form complexes since they have vacant d orbitals. They are also termed Coordination compounds. The organometallic compounds of the transition metals could be used as catalysts as well as reagents. For example, organocadmium, organozinc, organocopper, Grignard are used as the reagents for several reactions. Most of the complexes of organo transition metals are used as catalysts for many organic transformation reactions.

Question

The treatment of chlorobenzene with potassium amide in liquid ammonia results in the
formation of aniline. Propose four experiments to distinguish between the two mechanisms
given below
CI NH2
NH2
- Cl-
ÇI
NH2
NH2
+ NH3

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