The thermal decomposition of nitryl chloride is proposed to occur by the following mechanism: step 1 slow: NO2CI → NO2 + CI step 2 fast: CI + NO2CI –→ NO2 + Cl2 (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. (2) Which species acts as a catalyst? Enter formula. If none, leave box blank: (3) Which species acts as a reaction intermediate? Enter formula. If none, leave box blank: (4) Complete the rate law for the overall reaction that is consistent with this mechanism. (Use the form k[A]™[B]"... , where '1' is understood (so don't write it) for m, n etc.) Rate =

Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
Section14.6: Reaction Mechanisms
Problem 2RC: A reaction is believed to occur by the following mechanism: Stepl: 2AI (Fast equilibrium) Step 2: I...
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The thermal decomposition of nitryl chloride is proposed to occur by the following mechanism:
step 1
slow:
NO2CI → NO2 + CI
step 2
fast:
CI + NO2CI → NO2 + Cl2
(1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank.
+
+
(2) Which species acts as a catalyst? Enter formula. If none, leave box blank:
(3) Which species acts as a reaction intermediate? Enter formula. If none, leave box blank:
(4) Complete the rate law for the overall reaction that is consistent with this mechanism.
(Use the form k[A]m[B]"... , where '1' is understood (so don't write it) for m, n etc.)
Rate =
Transcribed Image Text:The thermal decomposition of nitryl chloride is proposed to occur by the following mechanism: step 1 slow: NO2CI → NO2 + CI step 2 fast: CI + NO2CI → NO2 + Cl2 (1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is not needed, leave it blank. + + (2) Which species acts as a catalyst? Enter formula. If none, leave box blank: (3) Which species acts as a reaction intermediate? Enter formula. If none, leave box blank: (4) Complete the rate law for the overall reaction that is consistent with this mechanism. (Use the form k[A]m[B]"... , where '1' is understood (so don't write it) for m, n etc.) Rate =
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