The pK1 for germanic acid, H,GEO3, is 9.0. Account for the increase in pK,1 of germanic acid compared to the structural analogue carbonic acid H,CO3.

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter20: Carboxylic Acids And Nitriles
Section20.4: Substituent Effects On Acidity
Problem 7P: Dicarboxylic acids have two dissociation constants, one for the initial dissociation into a...
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The pK1 for germanic acid, H,GeOz, is 9.0. Account for the increase in pK31 of
germanic acid compared to the structural analogue carbonic acid H2CO3.
O Higher clectronegativity of carbon compared to germanium
O Increased acidity of germanium comparcd to carbon
O Smaller ionic potential of carbon compared to germanium
O Higher clectronegativity of germanium compared
carbon
O Larger ionic potential of germanium compared to carbon
Transcribed Image Text:The pK1 for germanic acid, H,GeOz, is 9.0. Account for the increase in pK31 of germanic acid compared to the structural analogue carbonic acid H2CO3. O Higher clectronegativity of carbon compared to germanium O Increased acidity of germanium comparcd to carbon O Smaller ionic potential of carbon compared to germanium O Higher clectronegativity of germanium compared carbon O Larger ionic potential of germanium compared to carbon
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