The glycerol carbonylation reaction with CO₂ to produce glycerol carbonate (Figure 1) is thermodynamically hindered due to several reasons including the presence of water as a by-product and the stability of CO2 as a co-reactant. Discuss the possible approach to overcome the issues and be able to produce a higher yield of targeted glycerol carbonate. OH 0 Cat. + H₂O HO. LOH + CO₂ + НО. Figure 1

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The glycerol carbonylation reaction with CO₂ to produce glycerol carbonate (Figure 1) is
thermodynamically hindered due to several reasons including the presence of water as a
by-product and the stability of CO2 as a co-reactant. Discuss the possible approach to
overcome the issues and be able to produce a higher yield of targeted glycerol carbonate.
0
OH
0
Cat.
A
HO
LOH + CO₂
+ H₂O
HO.
Figure 1
Transcribed Image Text:The glycerol carbonylation reaction with CO₂ to produce glycerol carbonate (Figure 1) is thermodynamically hindered due to several reasons including the presence of water as a by-product and the stability of CO2 as a co-reactant. Discuss the possible approach to overcome the issues and be able to produce a higher yield of targeted glycerol carbonate. 0 OH 0 Cat. A HO LOH + CO₂ + H₂O HO. Figure 1
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