The first excited state of Ca is reached by absorption of 422.7-nm light. (a) What is the energy difference (J) between the ground and excited states? (b) The degeneracies are g*/g0  3 for Ca. Find N*/N0 at 2 500 K. (c) By what percentage will the fraction in (b) be changed by a 15-K rise in temperature? (d) Find N*/N0 at 6 000 K.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter20: Molecular Spectroscopy And Photochemistry
Section: Chapter Questions
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The first excited state of Ca is reached by absorption of 422.7-nm light. (a) What is the energy difference (J) between the ground and excited states? (b) The degeneracies are g*/g0  3 for Ca. Find N*/N0 at 2 500 K. (c) By what percentage will the fraction in (b) be changed by a 15-K rise in temperature? (d) Find N*/N0 at 6 000 K.

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