The characteristic orange light produced by sodium in a flame is due to the intense emission called the "D" streak from sodium. This "streak" is actually a doublet, whose wavelengths (measured in vacuum) are 589.15788 and 589.75537 nm. The refractive index of air in the vicinity of 589 nm is 1.0002926. Calculate the frequency, wavelength, and wave number of each component of the "D" line, measured in air.

Chemistry & Chemical Reactivity
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Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
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Chapter6: The Structure Of Atoms
Section6.3: Atomic Line Spectra And Niels Bohr
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The characteristic orange light produced by sodium in a flame is due to the intense emission called the "D" streak from sodium.

This "streak" is actually a doublet, whose wavelengths (measured in vacuum) are 589.15788 and 589.75537 nm.

The refractive index of air in the vicinity of 589 nm is 1.0002926.

Calculate the frequency, wavelength, and wave number of each component of the "D" line, measured in air.

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