Suppose the formation of nitryl fluoride proceeds by the following mechanism: elementary reaction rate constant NO₂ (g) +F₂ (g) → NO₂F (g)+F(g) k₁ F (g) +NO₂ (g) → NO₂F (g) k₂ Suppose also k₁ <

Chemistry for Engineering Students
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Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.36PAE: The reaction NO(g) + O,(g) — NO,(g) + 0(g) plays a role in the formation of nitrogen dioxide in...
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KINETICS AND EQUILIBRIUM
Writing the rate law implied by a simple mechanism with an initi...
Suppose the formation of nitryl fluoride proceeds by the following mechanism:
rate constant
k₁
k₂
step
elementary reaction
1 NO₂ (g) +F₂ (g) → NO₂F (g) +F (g)
2
F (g) + NO₂ (g) → NO₂F (g)
Suppose also k₁ << ₂. That is, the first step is much slower than the second.
Write the balanced chemical
equation for the overall
chemical reaction.
Write the experimentally-
observable rate law for the
overall chemical reaction.
Note: your answer should not
contain the concentrations of
any intermediates.
rate = k
ローロ
010
X
06
1/5
Transcribed Image Text:KINETICS AND EQUILIBRIUM Writing the rate law implied by a simple mechanism with an initi... Suppose the formation of nitryl fluoride proceeds by the following mechanism: rate constant k₁ k₂ step elementary reaction 1 NO₂ (g) +F₂ (g) → NO₂F (g) +F (g) 2 F (g) + NO₂ (g) → NO₂F (g) Suppose also k₁ << ₂. That is, the first step is much slower than the second. Write the balanced chemical equation for the overall chemical reaction. Write the experimentally- observable rate law for the overall chemical reaction. Note: your answer should not contain the concentrations of any intermediates. rate = k ローロ 010 X 06 1/5
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