Suppose the formation of nitrosyl chloride proceeds by the following mechanism: elementary reaction NO(g) + Cl₂ (g) → NOC1₂ (g) - NOC1₂ (g) + NO(g) → 2NOC1 (g) step 1 2 k₁ k₂ Suppose also k₁ <

Suppose the formation of nitrosyl chloride proceeds by the following mechanism: elementary reaction NO(g) + Cl₂ (g) → NOC1₂ (g) - NOC1₂ (g) + NO(g) → 2NOC1 (g) step 1 2 k₁ k₂ Suppose also k₁ <

Chemistry: Principles and Practice

3rd Edition

ISBN:9780534420123

Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer

Chapter13: Chemical Kinetics

Section: Chapter Questions

Problem 13.75QE

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Question

Suppose the formation of nitrosyl chloride proceeds by the following mechanism:
elementary reaction
NO(g) + Cl₂ (g) → NOC1₂ (g)
-
NOC1₂ (g) + NO(g) → 2NOC1 (g)
step
1
2
k₁
k₂
Suppose also k₁ <<k₂. That is, the first step is much slower than the second.
Write the balanced chemical
equation for the overall
chemical reaction.
Write the experimentally-
observable rate law for the
overall chemical reaction.
Note: your answer should not
contain the concentrations of
any intermediates.
0
rate constant
rate = k

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