Suggest possible crystallization solvents for the following compounds. Use IMF to predict the type of solvent each compound should be soluble in. Then, find the melting point and solubility of compounds in the handbook, and choose s recrystallization solvent
Suggest possible crystallization solvents for the following compounds. Use IMF to predict the type of solvent each compound should be soluble in. Then, find the melting point and solubility of compounds in the handbook, and choose s recrystallization solvent
Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter16: Amines
Section: Chapter Questions
Problem 16.34P
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Suggest possible crystallization solvents for the following compounds. Use IMF to predict the type of solvent each compound should be soluble in. Then, find the melting point and solubility of compounds in the handbook, and choose s recrystallization solvent
Transcribed Image Text:naphthale ne
0
4-phenylcyclohexanone
18.
2-inda nol
H₂CO₂C
phenylacetic acid
H
CO₂H
*$HOOO
dimethylfumarate
Transcribed Image Text:Solvent
6
Petroleum ether
Pentane
Hexane
Heptane
Ligroin
Heptane
Octane
Nonane
Cyclohexane
1,4-Dioxane
Tolnene
Diethyl ether
Chloroform
Ethyl acetate
Tetrahydrofuran
Dichloromethane
Acetone
Ethanol (95%)
Methanol
Water
CH3CH₂CH₂CH₂CH₂
pentane
CHỊCH,-O-CH;CH
diethyl ether
CH₂ CH₂
acetone
F7
Y
Table 1. Common solvents,
Dielectric Boiling Point Freezing Point
Constant (8)
°C (760 Torr)
&
7
1.9
1.84
1.89
FB
1.9
1.9
E
1.9
1.9
1.965
2.21
2.38
4.34
4.81
6.02
7.60
9.08
8
20.7
24,6
32.6
78.5
CH₂-C
********** **38
30-80
*
8
80-120
Ở–CH,CH,
ethyl acetate
CH₂CH₂-OH
ethanol
366
JOUL
H|J
"C
885 55 85 233 553-
-130
F10
(
9
95
-91
91
-57
-SI
6.6
118
95
CH₂CH₂CH₂CH₂CH₂CH₂CH₂CH₂
octane
-116
-63-5
-84
-109
295
-95
-11
94
10
Density
g/mL.
0.63
0.66
F11
T-PAD
0.68
18 19
)
0.68
0
-0.70
0.72
0.78
1.03
0.87
ALIENWARE
0.71
1.48
0.90
0.89
1.33
0.79
0,79
0.79
8-8-8
1.00
CH₂-OH
methanol
Water
Soluble
22222222 222 2222 9098
No
No
No
No
No
No
Yes
No
Slightly
Yes
Yes
Yes
na
Página <
F12
ALIENT
Flammable
K L :
||
Yes
Yes
Yes
الشالشال
Yes
Yes
Yes
Yes
Yes
Ves
cyclohexane 1,4-dioxane toluene
Yes
Yes
CH₂Cl₂
CHCI
tetrahydrocuran dichloromethane chloroform
Yes
No
Yes
Yes
No
Yes
Yes
Yes
No
H₂O
water
9
HOME
{
CH₂
+
=
3
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