Substitution and elimination reactions can be in direct competition. Predict the mechanism(s) that will predominate in the reaction shown. O Sn1 O Sn2 E1 E2 Sn2 & E2 O Sn1 & E1 Br NaSH DMSO ?
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- Which synthetic route(s) would complete the reaction shown? Br || ||| I and II O I and III ? HO OH + enantiomer Synthesis I: 1. NaCCCH3; 2. Na/NH3(I) ;3. OsO4; 4. NaHSO3, H₂O Synthesis II: 2. NaCCCH3; 2. H2, Lindlar's catalyst; 3. MCPBA; 4. aq. H₂SO4 Synthesis III: 1. NaCCCH3; 2. H₂, Pt; 3. MCPBA; 4. aq. H₂SO4can you explain how can we determine major and minor product from these reaction elimination-addition? &=&=1561=6, NH₂ majo CH, NH₂ NH₂ &=-&-&-& majo CH3 OCH, CI NINH, NH 3liq. KNH₂ NH309. Br ΚΝΗ, NH CI CH₁ 80 80 OCH, majo NH, NH₂ mino CH3 mino NH₂ NH₂ NH, NH, CI majo CH3 majo NH₂ NH₂What reagents are appropriate to carry out the conversion shown? - OH LOM 1. mCPBA; 2. CH3MgBr; 3. H₂O O 1. CH3MgBr; 2. H₂O O 1. mCPBA; 2. H₂O O mCPBA + enantiomer
- ew fopics] Draw the major organic product of the reaction shown below. H2SO4 HO, • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. C opy aste [F ChemDoodleConsider the reaction scheme shown below. HCI [1] ОН (a) Provide a detailed mechanism for reaction [1].1. .CI HC C: Li HC CH LICI 2. -CH3 OH Aqueous HO-S- -CH3 acetone g = SN1 Nucleophilic substitution Electrophilic a = Proton transfer addition h = SN2 Nucleophilic substitution b = Lewis acid/base e = El Elimination c = Radical chain f= E2 Elimination substitution Identify the mechanism by which each of the reactions above proceeds from the mechanisms listed. Use the letters a - i for your answers. among 1. 2.
- (b) How can be prepared from OEt CO,Et and at EtO OEt EtO2C 95 °C ? Provide the mechanism.Identify the major product of the reaction of an alkene shown below. ||| 1. Hg(OAc)2, H2O 2. NaBH4, NaOH ....... ОН || IV ОН о, ОНPlastic photochromic sunglasses are based on the following reversible rearrangement of a dye inside the lenses that occurs when the lenses are exposed to sunlight. The original dye absorbs UV light but not visible light and is thus colorless, while the rearrangement product absorbs visible light and is thus darkened. (a) Show the mechanism of the rearrangement. (b) Why does the rearrangement product absorb at a longer wavelength (visible light) than the original dye (UV)?
- The reactants, intermediates, final products, and all curved arrows showing bonds forming andbreaking are collectively referred to as the mechanism of a reaction. For the following reactants: a. Explain why the original statement of Markovnikov’s rule does not help in this case, but themodern restatement of Markovnikov’s rule tells you which carbon will get the X (Cl). b. Show the mechanism of the most likely addition reaction between the reactants.Provide a stepwise synthesis of 1-cyclopentylethanamine using the Gabriel synthesis. NH NK NH HO. OH NH2 Кон; ;H3O+ KOH; ;H30* "Br LIAIH4; ; H3O* Br LIAIH4;3) wite down the open structures of A, B, C and D wfth the reactions the Tyn thes is D, scheme showing given in synthesis the of trust. of pheromone H-CミC- H 1) NANH2 l18quid NHg -78°C. 2) 1- bromo-5-methyl hexone 3(Cg Hgb) 1) NANH2//iquid NHs/-78 °C A (CaHi6) 2) 1-bromodecane P-2 (Nez B)/He . cicuHu) CiHg Cog H D(Cig H3pO) 19 19 CS CamScanner ile tarandı