sorbed molecule. Solve the probler e partition function of the system. nolecules.]

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4) A surface with No adsorption centers has N (S N,) gas molecules adsorbed on it. Show that the
chemical potential of the adsorbed molecules is given by u = kTIn-
N
(No-N)a(T)
where a(T) is the
partition function of a single adsorbed molecule. Solve the problem by constructing the grand
partition function as well as the partition function of the system. [Neglect the intermolecular
interaction among the adsorbed molecules.]
Transcribed Image Text:4) A surface with No adsorption centers has N (S N,) gas molecules adsorbed on it. Show that the chemical potential of the adsorbed molecules is given by u = kTIn- N (No-N)a(T) where a(T) is the partition function of a single adsorbed molecule. Solve the problem by constructing the grand partition function as well as the partition function of the system. [Neglect the intermolecular interaction among the adsorbed molecules.]
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